In this work, the catalytic activity of three different sizes of gold nano particles (AuNPs) (12, 30, and 45 nm) synthesized by the citrate reduction process studied in the conventional redox reaction of KFe (CN) to KFe (CN) using NaBH(reductant) at four different temperatures (5 °C, 10 °C, 15 °C, and 20 °C) and measured by UV-visible spectrophotometry. Comparative kinetic analysis of different sizes of AuNPs including rate constant, activation energy, Entropy values and Frequency of collisions are reported for the first time. Transmission electron microscopy analysis is employed to investigate morphology and particle size.
View Article and Find Full Text PDFComput Intell Neurosci
October 2022
Game theory is an excellent mathematical tool to describe the interaction between the immune system and cancerous leukocytes (.). The feature of cancerous leukocytes to differentiate and mutate to give rise to leukemia is in the domain of ecological models as well.
View Article and Find Full Text PDFDuring the past few years, freelancing has grown exponentially due to the pandemic and subsequent economical changes in the world. In fact, in the last ten years, a drastic increase in freelancing has been observed; people quit their jobs to be their own boss. There are various reasons for this: downsizing of employees, not having fun in their jobs, unemployment, part time work to earn more, etc.
View Article and Find Full Text PDF. Currently, the COVID-19 pandemic represents a critical issue all over the world. On May 11, 2020, at 05 : 41 GMT, approximately 0.
View Article and Find Full Text PDFThis report examines the heat and mass transfer in three-dimensional second grade non-Newtonian fluid in the presence of a variable magnetic field. Heat transfer is presented with the involvement of thermal relaxation time and variable thermal conductivity. The generalized theory for mass flux with variable mass diffusion coefficient is considered in the transport of species.
View Article and Find Full Text PDFThe objective of this paper is to study oscillation of fourth-order neutral differential equation. By using Riccati substitution and comparison technique, new oscillation conditions are obtained which insure that all solutions of the studied equation are oscillatory. Our results complement some known results for neutral differential equations.
View Article and Find Full Text PDF