Using heterodyne transient grating spectroscopy, we observe a significant enhancement of exciton diffusion in a monolayer WSe stacked on graphene. The diffusion dynamics can be optically tuned within a few picoseconds by altering the photoexcited carrier density in graphene. The effective diffusion constant in initial picoseconds in the WSe/graphene heterostructure is (40.
View Article and Find Full Text PDFThe mechanisms controlling transport and retention of microplastics (MPs) in riverine systems are not understood well. We investigated the impact of large roughness elements (LREs) on in-stream transport and retention of the ubiquitous polystyrene-microplastics (PS-MPs). Scaled experiments were conducted with and without LREs under various shear Reynolds numbers (Re*) in an ecohydraulics flume.
View Article and Find Full Text PDFResearchers are searching for ways to better quantify methane emissions from natural gas infrastructure. Current indirect quantification techniques (IQTs) allow for more frequent or continuous measurements with fewer personnel resources than direct methods but lack accuracy and repeatability. Two IQTs are Other Test Method (OTM) 33A and Eddy Covariance (EC).
View Article and Find Full Text PDFCoastal wetlands provide key ecosystem services, including substantial long-term storage of atmospheric CO in soil organic carbon pools. This accumulation of soil organic matter is a vital component of elevation gain in coastal wetlands responding to sea-level rise. Anthropogenic activities that alter coastal wetland function through disruption of tidal exchange and wetland water levels are ubiquitous.
View Article and Find Full Text PDFSci Total Environ
May 2022
We investigated the hypothesis of emergent 'biogeochemical' similitude (parametric reduction) and scaling of dissolved oxygen (DO) in coastal streams across the U.S. Atlantic Coast by employing dimensional analysis methodology from fluid mechanics and hydraulic engineering.
View Article and Find Full Text PDFBackground/objectives: Other medical specialties have studied how their practices influence the environment, but environmental impact studies in the field of dermatology remain limited. With respect to dermatology, vehicle emissions by patients traveling to and from appointments are an important factor influencing climate change. This study was undertaken to determine the greenhouse gas emissions avoided by managing isotretinoin virtually at West Virginia University Hospital.
View Article and Find Full Text PDFThis study aims to evaluate the individual and synergistic controls of climatic and land cover changes on stormwater runoff regimes, and perform a comparative synthesis of the historical and future runoffs for complex coastal-urban environments. A large-scale (7117 km) mechanistic hydrologic model was developed for Florida Southeast Coasts Basin as the study area using U.S.
View Article and Find Full Text PDFWe investigated the ecological parameter reductions (termed "similitudes") and characteristic patterns of the net uptake fluxes of carbon dioxide (CO) in coastal salt marshes using dimensional analysis method from fluid mechanics and hydraulic engineering. Data collected during May-October, 2013 from four salt marshes in Waquoit Bay and adjacent estuary, Massachusetts, USA were utilized to evaluate the theoretically-derived dimensionless flux and various ecological driver numbers. Two meaningful dimensionless groups were discovered as the light use efficiency number (LUE = CO normalized by photosynthetically active radiation) and the biogeochemical number (combination of soil temperature, porewater salinity, and atmospheric pressure).
View Article and Find Full Text PDFThe primary responsibility for continuously discharging toxic organic pollutants into water bodies and open environments is the increase in industrial and agricultural activities. Developing economical and suitable methods to continuously remove organic pollutants from wastewater is highly essential. The aim of the present research was to apply response surface methodology (RSM) and artificial neural networks (ANNs) for optimization and modeling of photocatalytic degradation of acid orange 7 (AO7) by commercial TiO-P25 nanoparticles (TNPs).
View Article and Find Full Text PDFA systematic data analytics was employed to determine the relative linkages of stream water quality and environmental health with the land use and hydrologic drivers in the coastal-urban watersheds of southeast Florida. Power law-based partial least squares regression models were developed to reliably estimate the linkages by appropriately resolving multicollinearity (Nash-Sutcliffe efficiency = 0.72-0.
View Article and Find Full Text PDFWe used a simple, systematic data-analytics approach to determine the relative linkages of different climate and environmental variables with the canopy-level, half-hourly CO2 fluxes of US deciduous forests. Multivariate pattern recognition techniques of principal component and factor analyses were utilized to classify and group climatic, environmental, and ecological variables based on their similarity as drivers, examining their interrelation patterns at different sites. Explanatory partial least squares regression models were developed to estimate the relative linkages of CO2 fluxes with the climatic and environmental variables.
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