Development of Composite Nanostructured Electrodes for Water Desalination via Membrane Capacitive Deionization.

Novel two-layer nanostructured electrodes are successfully prepared for their application in membrane capacitive deionization (MCDI) processes. Nanostructured carbonaceous materials such as graphene oxide (GO) and carbon nanotubes (CNTs), as well as activated carbon (AC) are dispersed in a solution of poly(vinyl alcohol) (PVA), mixed with polyacrylic acid (PAA) or polydimethyldiallylammonium chloride (PDMDAAC), and subsequently cast on the top surface of an AC-based modified graphite electrode to form a thin composite layer that is cross-linked with glutaraldehyde (GA). Cyclic voltammetry (CV) is performed to investigate the electrochemical properties of the composite electrodes and desalination experiments are conducted in batch mode using a MCDI unit cell to investigate the effects of i) the nanostructured carbonaceous material, ii) its concentration in the polymer blend, and iii) the molecular weight of the polymers on the desalination efficiency of the system.