The development of a novel, green, efficient, and eco-friendly GC-MS/MS analytical method for the reliable and rapid determination of dl-PCBs, and PCDD/Fs using hydrogen as a carrier gas and a modified ion source.

The polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) are worldwide contaminants, and they tend to accumulate in wide variety of matrices. Therefore, due to the highest accumulation rate and recalcitrancy, their precise quantification makes significant concern about their toxicological effects on both humans and organisms. The objective of the study is that using hydrogen carrier gas instead of helium in gas chromatography with triple quadrupole (GC-MS/MS) systems could contribute to improvements on the analysis of dl-PCBs and PCDD/Fs in environmental matrices.

Ecotoxicological risk assessments and components of persistent organic pollutants and metals in the historical settlement area (Iznik (Nicea) lake) large water resource sediments.

The main objectives of this study are to measure permanent organic and inorganic pollutants in detail in an area that hosts historical structures underneath and feeds the huge ecosystem with water, to reveal risk values. Total PAH concentrations in the samples ranged from 43.41 to 202.

Evaluation of hexabromocyclododecane (HBCD), polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) outflows during the destruction of HBCD wastes in a hazardous waste incinerator.

This paper presents an evaluation of hexabromocyclododecane (HBCD), polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) outflows during the destruction of HBCD waste stockpiles in IZAYDAS Hazardous Waste Incinerator (HWI) in Kocaeli, Türkiye. HBCD wastes containing 100 % pure HBCD were in 25 kg packages with 63 % Br content were co-incinerated in a 3-day test burn with average feed rate of 26 kg/h. HBCD, PBDD/Fs and PCDD/Fs were measured in the outlet streams to quantify the amount of unintended POPs releases associated with the processing of HBCD waste and to observe the POP removal performance of air pollution control equipment (APCE) of the incinerator.

Kinetics of Microwave-Assisted Extraction Process Applied on Recovery of Peppermint Polyphenols: Experiments and Modeling.

The aim of this work was to investigate the microwave-assisted extraction (MAE) kinetics of polyphenolic compounds from organic peppermint leaves. The phytochemicals of peppermint ( L.) are increasingly used in food technology due to their numerous biological activities.

A comprehensive assessment, source input determination and distribution of persistent organic pollutants (POPs) along with heavy metals (HMs) in reservoir lake sediments from Çanakkale province, Türkiye.

This study presents the distribution of persistent organic pollutants (POPs), polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs) in the sediments from four dams and two ponds in the Çanakkale city, Türkiye. The total concentration varied from 41.47 to 145.

Antimicrobial and antioxidant activity of phenolic extracts from walnut () green husk by using pressure-driven membrane process.

Unlabelled: In this study, antioxidant (DPPH and metal chelating), DNA cleavage, biofilm, and antimicrobial properties of extracted phenol from the walnut green husk (WGH) and its different concentrate and permeate samples were evaluated. For maximum phenolic compound extraction from the WGH first, the effects of solvent type (deionized water, methanol, n-hexane, acetone, and ethanol), solvent temperature (25-75 °C), and extraction time (0.5-24 h) were optimized.

Determination of PCDD/F and DL-PCB pollution levels, source appointment and risk assessment of surface sediments in dam lakes in Istanbul, Türkiye.

The current situation of the water resources of Istanbul, which is one of the important metropolises of Europe, should be known and constantly monitored by the reasons of the rapid increase in the city population, the acceleration of production-related industrial activities, the expansion of the city with construction activities, and the decrease in precipitation. The purpose of this study was to reveal the situations of surface sediments collected from Istanbul water reservoirs in terms of PCDD/Fs and DL-PCBs, to identify possible sources, and to conduct their ecological risk assessment. Total PCDD/Fs and DL-PCBs concentrations varied between 28.

Spatial distribution, source identification and ecological risk assessment of POPs and heavy metals in lake sediments of Istanbul, Turkey.

Istanbul needs to be protected and constantly monitored water resources due to its increasing population and the decrease in precipitation. This study aims to comprehensively reveal surface sediments collected from reservoirs that supply water to Istanbul concerning POPs (PAHs, PCBs, and OCPs) and heavy metals; to identify possible sources of PAHs, and conduct their ecological risk assessment. Pollution indices in this study were used as contamination degree (CD) contamination factor (CF), geoaccumulation index (I), pollution load index (PLI) and Sediment Quality Guidelines (SQGs).

Spatial distribution and source identification of persistent organic pollutants in the sediments of the Yeşilırmak River and coastal area in the Black Sea.

Surface sediments from the Yeşilırmak River and the near coastal area in the Black Sea were collected using sediment traps to assess the spatial distributions of persistent organic pollutants and find their potential sources. Analyses were carried out to determine the concentrations of the persistent organic pollutants of seventeen polychlorinated dibenzo-p-dioxins and dibenzofurans, sixteen polycyclic aromatic hydrocarbons, seven polychlorinated biphenyls, and eight organochlorine pesticides using high-resolution gas chromatography-mass spectrometry and gas chromatography-tandem mass spectrometry systems. Analysis showed that the three main components of persistent organic pollutants (polychlorinated dibenzo-p-dioxins and dibenzofurans, polycyclic aromatic hydrocarbons, and organochlorine pesticides) primary sources are industrial activities.

Occurrence of micropollutants in the Yesilirmak River Basin, Turkey.

The European Water Framework Directive (WFD) (2000/60/EC) is the most visionary piece of European environmental legislation that aims to achieve good water status of both surface water and groundwater bodies. The Directive provides a fundamental basis for surface water monitoring activities in the European Member States. The objective of this study is to investigate the occurrence of micropollutants in the Yesilirmak River and to develop a cost-effective monitoring strategy based on spatiotemporal data.

Applicability of purge and trap gas chromatography- mass spectrometry method for sensitive analytical detection of naphthalene and its derivatives in waters.

Nowadays, a wide variety of chemicals has emerged because of increasing industrial and human activities. Thus, environmental chemistry laboratories performing analytical measurements need rapid and sensitive methods more than ever to get reliable quantitative data. For this purpose, a purge and trap gas chromatography-mass spectrometry (GC-MS) method was developed and validated for the rapid, simple, and sensitive determination of the presence of naphthalene and its derivatives in waters.

Production of Bio-Based Pigments from Food Processing Industry By-Products (Apple, Pomegranate, Black Carrot, Red Beet Pulps) Using c.

Food processing industry by-products (apple, pomegranate, black carrot, and red beet pulps) were evaluated as raw materials in pigment production by the filamentous fungi The effect of fermentation conditions (solid and submerged-state), incubation period (3, 6, 9, 12, and 15 d), initial substrate pH (4.5, 5.5, 6.

Determination of 117 endocrine disruptors (EDCs) in water using SBSE TD-GC-MS/MS under the European Water Framework Directive.

The aim of this work is the highly sensitive determination of 117 contaminants in surface waters at very low concentrations. Gas chromatography-amenable priority compounds from the European Water Framework Directive (EWFD, 45 priority substances) and substances from the Turkish Regulation on the Management of Surface Water Quality (TRMSWQ, 250 substances) were analyzed. Almost a third to one half of the compounds in the TRMSWQ list were successfully detected in a single gas chromatography-tandem mass spectrometry (GC-MS/MS) injection.

Assessment of PCDD/F and dioxin-like PCB levels in environmental and food samples in the vicinity of IZAYDAS waste incinerator plant (WIP): from past to present.

The study includes the determination of the general background PCDD/F and dl-PCB levels in environmental (ambient air and soil) and food (meat, milk, egg, leafy vegetable, root vegetable and fruit samples) samples collected in four sampling sites in the vicinity of IZAYDAS WIP and its possible health risks. The local and meteorological conditions (prevailing wind direction, season, raining, and soil structure) were taken into account in the selection of sampling sites. The concentrations of PCDD/F and dl-PCB in ambient air ranged from 0.