The reaction of wood with maleic anhydride (MA) and sodium hypophosphite (SHP) has been identified as a viable modification method, with macroscopical properties indicating formation of cross-linking to explain the results. However, the chemical reaction between wood and the modification reagents has not been studied yet. To resolve this, the reaction was studied with solid-state C cross-polarization magic-angle-spinning (CP-MAS) and P MAS nuclear magnetic resonance (NMR) and X-ray photoelectron spectroscopy (XPS) to reveal the formation of bonds between wood components, MA and SHP during the treatments to explain the formation of cross-linking and the possible fixation of phosphorus in wood.
View Article and Find Full Text PDFIn this study, Kraft lignin was modified by ammonium dihydrogen phosphate (ADP) and urea for achieving phosphorylation and carbamylation, aiming to protect wood against biological and fire attack. Scots pine (Pinus sylvestris L.) sapwood was impregnated with a water solution containing Kraft lignin, ADP, and urea, followed by heat treatment at 150 °C, resulting in changes in the properties of the Kraft lignin as well as the wood matrix.
View Article and Find Full Text PDFNatural weathering test at two different European climatic zones were conducted to investigate simultaneously both, the fungal colonisation and weathering process of Scots pine wood ( L.). The hypothesis was that the wood performing differently in various climate conditions might affect fungal infestation.
View Article and Find Full Text PDFThe exterior application of fire-retardant (FR) timber necessitates it to have high durability because of the possibility to be exposed to rainfall. In this study, water-leaching resistance of FR wood has been imparted by grafting phosphate and carbamate groups of the water-soluble FR additives ammonium dihydrogen phosphate (ADP)/urea onto the hydroxyl groups of wood polymers via vacuum-pressure impregnation, followed by drying/heating in hot air. A darker and more reddish wood surface was observed after the modification.
View Article and Find Full Text PDFGuanyl-urea phosphate (GUP) was introduced into furfurylated wood in order to improve fire retardancy. Modified wood was produced via vacuum-pressure impregnation of the GUP-furfuryl alcohol (FA) aqueous solution, which was then polymerized at elevated temperature. The water leaching resistance of the treated wood was tested according to European standard EN 84, while the leached water was analyzed using ultra-performance liquid chromatography (UPLC) and inductively coupled plasma-sector field mass spectrometry (ICP-SFMS).
View Article and Find Full Text PDFThe objective of the work was to improve the leaching resistance of fire-retardant (FR) modified wood by the incorporation of a thermoset resin. Here, Scots pine ( L.) sapwood was impregnated with melamine formaldehyde (MF) resin and hydrophilic FRs guanyl-urea phosphate/boric acid by a vacuum-pressure treatment.
View Article and Find Full Text PDFThe objective of this study was to explore an effect of the combined inorganic materials on the wood hardness and flame-retardancy properties in a concept of sustainable material management. Herein, the reinforcement of Scots pine ( L.) sapwood with sodium silicate and TiO nanoparticles vacuum-pressure technique is reported.
View Article and Find Full Text PDFBackground: The genus is most exploitable xylotrophic fungi, with valuable biotechnological, medical, and nutritional properties. The relevant features of the representatives of this genus to provide attractive low-cost industrial tools have been reported in numerous studies to resolve the pressure of ecological issues. Additionally, a number of species are highly adaptive, do not require any special conditions for growth, and possess specific resistance to contaminating diseases and pests.
View Article and Find Full Text PDFDuring industrial wood drying, extractives migrate towards the wood surfaces and make the material more susceptible to photo/biodegradation. The present work provides information about the distribution, quantity and nature of lipophilic substances beneath the surface in air- and kiln-dried Scots pine (Pinus sylvestris L.) sapwood boards.
View Article and Find Full Text PDFStud Health Technol Inform
April 2018
While game accessibility has improved significantly the last few years, there are still barriers for equal participation and multiplayer issues have been less researched. Game balance is here about making the game fair in a player versus player competitive game. One difficult design task is to balance the game to be fair regardless of visual or hearing capabilities, with clearly different requirements.
View Article and Find Full Text PDF