Tracing pollution originating from uranium (U) mining activities is a key challenge due to the diversity of U sources (geochemical background versus U-ore) and its daughter radionuclides. Among the available tracers that can be used to highlight the impact of these activities on the environment, the application of Pb stable isotopes is relevant. This paper is an overview of the use of Pb isotopes for tracing U-mining impacts due to mining and milling activities.
View Article and Find Full Text PDFDiatoms and bacteria play a vital role in investigating the ecological effects of heavy metals in the environment. Despite separate studies on metal interactions with diatoms and bacteria, there is a significant gap in research regarding heavy metal interactions within a diatom-bacterium system, which closely mirrors natural conditions. In this study, we aim to address this gap by examining the interaction of uranium(VI) (U(VI)) with Achnanthidium saprophilum freshwater diatoms and their natural bacterial community, primarily consisting of four successfully isolated bacterial strains (Acidovorax facilis, Agrobacterium fabrum, Brevundimonas mediterranea, and Pseudomonas peli) from the diatom culture.
View Article and Find Full Text PDFHigh U concentrations (reaching up to 14,850 mg ⋅ kg), were determined in soils and sediments of a wetland downstream of a former U mine in France. This study aims to identify the origin of radioactive contaminants in the wetland by employing Pb isotope fingerprinting, (U/U) disequilibrium, SEM, and SIMS observations. Additionally, information about U and Ra transport processes was studied using U-238 series disequilibrium.
View Article and Find Full Text PDFWith the aim of improving the phytoextraction rate of cesium (Cs), the effect of Pseudomonas fluorescens ATCC 17400 and its siderophore pyoverdine (PVD) on the uptake of Cs by red clover was studied in soil pots. This work also provides a mechanistic understanding of the Cs-bacteria (or PVD)-illite-plant interactions by using a simplified experimental design, i.e.
View Article and Find Full Text PDFWithin the context of risk evaluation of chemical spillages into the marine environment, this paper reports on an offshore experiment to study the behaviour of styrene spilled into sea under natural conditions and discusses theoretical approaches. Floating structures were used to enclose the spillage and the gaseous cloud formation, and dissolution processes were in situ monitored. The identification of spill risks for man and marine environment through GESAMP's hazard profile is described for styrene: Styrene is rated as a chemical with a significant health hazard that will float but also evaporate.
View Article and Find Full Text PDFIt is shown that the surface-enhanced Raman scattering (SERS) technique can be applied to detect organic molecules during in situ experiments. To this purpose, we used trans-1,2-bis(4-pyridyl)ethylene (BPE) as a target molecule. Adsorbed on the SERS chemosensor surface and excited under laser, the vibration modes of the molecules can be identified.
View Article and Find Full Text PDFThis paper reports an accurate synthesis of surface-enhanced Raman scattering (SERS) active substrates, based on gold colloidal monolayer, suitable for in situ environmental analysis. Quartz substrates were functionalized by silanization with (3-mercaptopropyl)trimethoxysilane (MPMS) or (3-aminopropyl)trimethoxysilane (APTMS) and they subsequently reacted with colloidal suspension of gold metal nanoparticles: respectively, the functional groups SH and NH(2) bound gold nanoparticles. Gold nanoparticles were prepared by the chemical reduction of HAuCl(4) using sodium tricitrate and immobilized onto silanized quartz substrates.
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