Publications by authors named "Olivier Gorce"
Phys Chem Chem Phys
August 2006
Article Synopsis
- The study investigates a Rh-oxidised species in a specific Rh(0.29)/Ce0.68Zr0.32O2 catalyst with unusual CO-O2 kinetics, utilizing various analytical methods.
- Findings, particularly from N2-FTIR (first-time application on this catalyst), indicate that Rh exists primarily as electron-deficient clusters (Rhndelta+) after a reduction process at high temperature.
- Additionally, CO-FTIR experiments suggest that these electron-deficient species are influenced by the reduced support and neighboring Cl anions, while the presence of CO reveals RhI(CO)2 species as well.
