Dataset for the synthesis, characterisation and application of cobalt and nitrogen co-doped TiO nanoparticles on triclosan photodegradation using visible LED light.

The growing threat of emerging waterborne contaminants is a global concern, fuelled in part by the ineffectiveness of current remediation strategies. One of the most prominent remediation strategies is catalytic photodegradation, particularly with TiO nanoparticles (NPs), but its full utilization is hampered by using only UV radiation, which is scarce in sunlight. To fully benefit from the sunlight abundance, several efforts are focused on the tailoring of TiO to make it more active in visible (Vis) light.

Photocatalytic degradation of acetaminophen and caffeine using magnetite-hematite combined nanoparticles: kinetics and mechanisms.

The increased use of pharmaceutical and personal care products (PPCPs) has contributed to the contamination of water systems and put pressure on the development of new techniques to deal with this problem. Acetaminophen (paracetamol), a common analgesic and antipyretic drug, and caffeine, a known central nervous system stimulant, are being used frequently by many people and found in large amounts in wastewater systems. In this work, their removal, by photocatalytic degradation, was promoted using magnetic nanoparticles (NPs) based on iron oxides.

Comparative study on photocatalytic degradation of the antidepressant trazodone using (Co, Fe and Ru) doped titanate nanowires: Kinetics, transformation products and in silico toxicity assessment.

Titanate nanomaterials have been outstanding in the removal of emerging contaminants by the photocatalysis process. These photocatalysts, when modified through techniques such as doping with metals, they have advantages over TiO, especially in the region of visible light. In this work, the photocatalytic performance of four recent reported catalysts, pristine titanate nanowires, cobalt-doped titanate nanowires, iron-doped titanate nanowires and ruthenium-doped titanate nanowires, for the removal of the antidepressant trazodone under visible light radiation was compared.

A comparative study on emergent pollutants photo-assisted degradation using ruthenium modified titanate nanotubes and nanowires as catalysts.

Several methods have been used to tailor nanomaterials structure and properties. Sometimes, slight changes in the structure outcomes expressive improvements in the optical and photocatalytic properties of semiconductor nanoparticles. In this context, the influence of the metal doping and the morphology on a catalyst performance was studied in this work.

Photocatalytic degradation of cyclophosphamide and ifosfamide: Effects of wastewater matrix, transformation products and in silico toxicity prediction.

Antineoplastic drugs have been identified in surface water and effluents from wastewater treatment and, once in the environment, may be harmful to aquatic organisms, as these compounds are possibly mutagenic, genotoxic, cytotoxic, carcinogenic and teratogenic. This work investigated the photodegradation of cyclophosphamide (CP) and ifosfamide (IF) using ruthenium doped titanate nanowires (Ru-TNW) in distilled water (DW) and in wastewater (WW) from secondary wastewater treatment, under UV-Vis radiation. The results indicated that Ru-TNW showed photocatalytic activity for the two cytotoxic drugs with the half-life (t) of 15.

Degradation of duloxetine: Identification of transformation products by UHPLC-ESI(+)-HRMS/MS, in silico toxicity and wastewater analysis.

Duloxetine (DUL), an antidepressant drug, has been detected in surface water and wastewater effluents, however, there is little information on the formation of its transformation products (TPs). In this work, hydrolysis, photodegradation (UV irradiation) and chlorination experiments were performed on spiked distillated water, under controlled experimental conditions to simulate abiotic processes that can occur in the environment and wastewater treatment plants (WWTPs). Eleven TPs, nine from reaction with UV light and two from chlorine contact, were formed and detected by ultra-high performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry, and nine of them had their chemical structures elucidated upon analyses of their fragmentation patterns in MS/MS spectra.

Transformation products of citalopram: Identification, wastewater analysis and in silico toxicological assessment.

The objective of this study was to identify transformation products (TPs) of citalopram (CIT), an antidepressant drug, in laboratory experiments. Moreover, toxicity predictions and analyzes in wastewater samples were performed. For the formation of TPs, raw water was used for the processes of hydrolysis; photodegradation under ultraviolet (UV) irradiation and chlorination.

Biotechnologically obtained nanocomposites: A practical application for photodegradation of Safranin-T under UV-Vis and solar light.

This research was undertaken to determine the potential of biologically obtained ZnS-TiO2 nanocomposites to be used as catalysts in the photodegradation of organic pollutants, namely, Safranin-T. The photocatalysts were prepared by modifying the surface of commercial TiO2 particles with naturally produced ZnS, using sulfide species produced by sulfate-reducing bacteria and metal contaminated wastewaters. Comparative studies using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM), prior and after photodegradation, were carried out in order to monitor possible structural and morphological changes on the particles.

Zinc sulfide nanocoating of silica submicron spheres using a single-source method.

A chemical method to coat submicron silica particles with nanocrystalline zinc sulfide is described. The ZnS nanocoating was obtained by the thermalysis of zinc diethyldithiocarbamate in the presence of morphologically well defined silica particles. The powders obtained were isolated and were characterized by UV/visible optical reflectance, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS).

Optical properties of the synthetic nanocomposites SiO2/CdS/poly(styrene-co-maleic anhydride) and SiO2/CdS/poly(styrene-co-maleimide).

Hybrid materials consisting of SiO2/CdS particles dispersed in poly(styrene-co-maleic anhydride) and poly(styrene-co-maleimide) have been synthesized and characterized. The polymer nanocomposites were synthesised in situ in the presence of previously prepared inorganic fillers (SiO2/CdS). The nanocomposites were synthesized with the use of as-prepared or surface-modified SiO2/CdS fillers.