Second harmonic generation on crystalline organic nanoclusters under extreme nanoconfinement in functionalized silica-benzil composites.

We demonstrate a series of organic-inorganic nanocomposite materials combining the mesoporous silica (PS) and benzil (BZL) nanocrystals embedded into its nanochannels (6.0-13.0 nm in diameter) by capillary crystallization.

Anisotropic confinement of chromophores induces second-order nonlinear optics in a nanoporous photonic metamaterial.

Second-order nonlinear optics is the base for a large variety of devices aimed at the active manipulation of light. However, physical principles restrict its occurrence to non-centrosymmetric, anisotropic matter. This significantly limits the number of base materials exhibiting nonlinear optics.