Mechanism and Kinetics of the Phase Formation and Dissolution of NaWO on a Pt Electrode in a NaWO-WO Melt.

A comprehensive study concerning the phase formation mechanism and growth/dissolution kinetics of sodium tungsten bronze crystals during the electrolysis of a 0.8NaWO-0.2WO melt was carried out.

Simulation of 3D Electrochemical Phase Formation: Mixed Growth Control.

Processes of nucleation and growth largely determine the structure and properties of thin films obtained by electrodeposition on foreign substrates. Theoretical aspects of the initial stages of electrochemical phase formation under constant and variable overpotentials are considered in this work. Simulation of multiple nucleation with mixed (charge transfer, and diffusion) controlled growth was performed for three cases (cyclic voltammetry, potentiostatic electrodeposition, and galvanostatic electrodeposition).