Characteristics and Challenges of Poly(ethylene--vinyl acetate) Solution Electrospinning.

Poly(ethylene--vinyl acetate) (PEVA) is a versatile elastic, durable, and biocompatible copolymer, which can be processed by melt extrusion or solvent casting, while electrospinning has been reported as challenging. Here, a spinnability window should be identified using a total of 10 different PEVA materials with increasing vinyl acetate content (∼12-40 wt %) and molecular weights (∼60-130 kDa). Based on the solubility predictions by calculating Hansen solubility parameters, candidate solvents were experimentally evaluated.

Stereochemical Heterogeneity Analysis of Polylactides by Multidimensional Liquid Chromatography.

A new and robust high-performance liquid chromatography (HPLC) method that separates poly(lactic acid) (PLA) according to its stereochemical composition is presented. Using this method, poly(l-lactide) incorporating trace amounts of -lactide resulting from the racemization is separated from the pristine polymer. To prove this aspect in more detail, a representative poly(l-lactic acid) standard, assumed to be highly homogeneous, was separated using this method.