Publications by authors named "O Yamamuro"

Article Synopsis
  • Understanding water dynamics is crucial across various fields, and recent research has identified metastable states of water clusters in hydrophobic solvents using H nuclear magnetic resonance spectroscopy.
  • The study utilized quasi-elastic neutron scattering to investigate the slow diffusion dynamics of these water clusters in benzene, revealing that their movement is significantly slower than that of bulk water.
  • Even at temperatures above freezing (283-303 K), the dynamics of water clusters were found to be comparable to that of ice, showing a self-diffusion coefficient much lower than expected.
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Water-in-salt electrolytes have attracted considerable interest in the past decade for advanced lithium-ion batteries, possessing important advantages over the non-aqueous electrolytes currently in use. A battery with a LiTFSI-water electrolyte was demonstrated in which an operating window of 3 V is made possible by a solid-electrolyte interface. Viscosity is an important property for such electrolytes, because high viscosity is normally associated with low ionic conductivity.

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The dynamics of water and agarose molecules in an agarose aqueous solution has been studied by means of quasielastic neutron scattering (QENS). The dynamic structure factor (,) of the agarose aqueous solution was fitted well to the sum of the Lorentz and delta function. The former is attributed to the diffusive motion of water molecules and the latter to the local vibrational motion of agarose molecules.

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Dedicated breast positron emission tomography (db-PET) is more sensitive than whole-body positron emission tomography and is thus expected to detect early stage breast cancer and determine treatment efficacy. However, it is challenging to decrease the sensitivity of the chest wall side at the edge of the detector, resulting in a relative increase in noise and a decrease in detectability. Longer acquisition times and injection of larger amounts of tracer improve image quality but increase the burden on the patient.

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The availability of sufficient amounts of form I of benzocaine has led to the investigation of its phase relationships with the other two existing forms, II and III, using adiabatic calorimetry, powder X-ray diffraction, and high-pressure differential thermal analysis. The latter two forms were known to have an enantiotropic phase relationship in which form III is stable at low-temperatures and high-pressures, while form II is stable at room temperature with respect to form III. Using adiabatic calorimetry data, it can be concluded, that form I is the stable low-temperature, high-pressure form, which also happens to be the most stable form at room temperature; however, due to its persistence at room temperature, form II is still the most convenient polymorph to use in formulations.

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