Publications by authors named "O Soltwedel"

Correction for 'Structure formation of PNIPAM microgels in foams and foam films' by Matthias Kühnhammer , , 2022, , 9249-9262, https://doi.org/10.1039/D2SM01021F.

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We investigate the wetting properties of PDMS (Polydimethylsiloxane) pseudo-brush anchored on glass substrates. These PDMS pseudo-brushes exhibit a significantly lower contact angle hysteresis compared to hydrophobic silanized substrates. The effect of different molar masses of the used PDMS on the wetting properties seems negligible.

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Two polyaspartates bearing -fluorinated azobenzenes (FAB) as photo-responsive groups in the side chain were synthesized: PFABLA () and co-polyaspartate PpFABLA--PBLA [, 75%(n/n) PFABLA content]. As a consequence of the /-isomerization of the side chain, PFABLA () undergoes a visible-light-induced reversible coil-helix transition in solution: Green light (525 nm) affords the coil, and violet light (400 nm) affords the helix. FAB significantly increases the thermal stability of the -isomer at 20 °C ( = 66 d for the -isomer) and effectively counters the favored back formation of the helix.

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Responsive aqueous foams are very interesting from a fundamental point of view and for various applications like foam flooding or foam flotation. In this study thermoresponsive microgels (MGs) made from poly(-isopropyl-acrylamide) (PNIPAM) with varying cross-linker content, are used as foam stabilisers. The foams obtained are thermoresponsive and can be destabilised by increasing the temperature.

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The modelling of scattering data from foams is very challenging due to the complex structure of foams and is therefore often reduced to the fitting of single peak positions or feature mimicking. This article presents a more elaborate model to describe the small-angle neutron scattering (SANS) data from foams. The model takes into account the geometry of the foam bubbles and is based on an incoherent superposition of the reflectivity curves arising from the foam films and the small-angle scattering (SAS) contribution from the plateau borders.

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