This study investigates the catalytic potential of anionic MnO nanosheets (Mn), a cationic covalent organic Framework (COF), and their composites (CM, C2M, and CM2) with varying Mn weight percentages for arsenic removal from groundwater. The catalysts were used as activators of sodium sulfite (SS) under light conditions, enabling the pre-oxidation of arsenic (III) (As3) to arsenic(V) (As5), followed by the adsorption of As5 for complete arsenic removal from water. The Mn-COF-SS systems (C2M, CM, CM2) exhibited superior performance compared to Mn and COF alone, highlighting the dual functionality of the composites as both oxidizing agents and effective adsorbents for arsenic species.
View Article and Find Full Text PDFRechargeable zinc-air batteries (RZABs) have been described as one of the most viable next-generation battery technologies, especially due to their low cost, high capacity, and being environmental-friendly. In this work, hausmannite MnO nanoparticles, obtained from low-cost commercial electrolytic manganese dioxide, were dispersed on conductive multiwalled carbon nanotubes (CNTs) and carbon nanofibers (CNFs) and investigated for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in an alkaline medium and then applied in RZAB cell. The high performance of the CNFs (in terms of electron transfer kinetics) over the CNTs has been associated with its inherent defects and nitrogen content.
View Article and Find Full Text PDF