The ubiquitousness of per- and polyfluoroalkyl substances (PFAS) is a big concern and PFAS remediation is urgently needed such as via degradation. While previous studies have explored ultrasonic degradation of PFAS, work evaluating the operational parameters is rare, especially concerning real wastes such as aqueous film-forming foam (AFFF) and foam fractionate (FF). This study investigates the key operational parameters affecting the degradation efficiency of PFAS, encompassing ultrasonication frequency (580-1144 kHz), power intensity (125-187.
View Article and Find Full Text PDFWhile microplastics and nanoplastics are emerging as a big environmental concern, their characterization is still a challenge, particularly for identification and simultaneous quantification analysis where imaging via a hyper spectrum is generally needed. In the past few years, Raman imaging has been greatly advanced, but the analysis protocol is complicated and not yet standardized because imaging analysis is different from traditional analysis. Herein we provide a step-by-step demonstration of how to employ confocal Raman techniques to image microplastics and nanoplastics.
View Article and Find Full Text PDFThe concern over plastic contamination has led to bans on plastic shopping bags, often replaced by paper ones. However, logos painted or printed on paper bags may still contain plastics, as investigated herein. In some logos, for example, white pigment of titanium dioxide (TiO) nanoparticles are bound with plastic binder onto the cellulose surface of the paper.
View Article and Find Full Text PDFAir balloons are a ubiquitous presence in our daily lives, and their rupture may release a substantial quantity of debris, as investigated herein. We employ Raman imaging to capture the fragments resulting from balloon explosions, enabling the identification and direct visualisation of minute microplastic particles / fragments with an improved signal-to-noise ratio for precise quantification. To circumvent the generation of misleading confocal Raman images, we recommend employing terrain mapping to scan the three-dimensional surface of the sample.
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