Benz(2-heteroaryl)cyanoximes and their Tl(i) complexes: new room temperature blue emitters.

A series of five 2-heteroarylcyanoximes such as: alpha-oximino-(2-benzimidazolyl)acetonitrile (HBIHCO), alpha-oximino-(N-methy-l-2-benzimidazolyl)acetonitrile (HBIMCO), alpha-oximino-(2-benzoxazolyl)acetonitrile (HBOCO), alpha-oximino-(2-benzothiazolyl)acetonitrile (HBTCO) and alpha-oximino-(2-quinolyl)acetonitrile (HQCO) and their monovalent thallium(i) complexes were synthesized and characterized using spectroscopic methods ((1)H, (13)C NMR, IR, UV-visible, mass-spectrometry) and X-ray analysis. The HBIMCO (as monohydrate) adopts planar trans-anti configuration in the solid state. The crystal structure of "HBOCO" revealed the presence of nitroso anion a, BOCO(-), and protonated oxime cation b, H(2)BOCO(+), that form a H-bonded dimer in the unit cell.

Binding of phosphate with a simple hexaaza polyammonium macrocycle.

A mixture of dihydrogen phosphate and phosphoric acid has been crystallized with a hexaprotonated 26-membered polyammonium macrocycle, 1,4,7,14,17,20-hexaazacyclohexacosane, as the counterion. The complex crystallizes in the monoclinic space group P2(1)/c with unit cell parameters of a = 10.006(2) A, b = 12.

[The assessment of the psychophysiological status of patients with duodenal peptic ulcer].

Clinicopsychologic and psychophysiologic evaluation was done in 290 patients with duodenal ulcer during the stage of exacerbation. The results obtained suggest the levels of vegetative lability, anxiety and depression in the above patients to be significantly higher by comparison with those in healthy subjects. The degree of neuropsychic disorders depends upon the type of personal response to the illness which is greater in women than it is in men.

[A differential approach to the correction of psychosomatic dysadaptation in patients with duodenal peptic ulcer].

Studied were psychologic features of 169 patients with duodenal ulcer. Complexes were devised of differentiated psychotherapeutic treatment suitable for the revealed four variants of psychosomatic dysadaptation manifested by patients. Institution of complexes of psychotherapeutic treatment using electromagnetic radiation of the MWF range resulted in rapid healing of ulcerous lesion, sooner disappearance of the painful syndrome compared with the control group patients who had received medicamentous treatment only.