The last decade saw myriad new donor polymers, among which benzodithiophene-co-thienothiophene polymers are attractive due to their relatively high power conversion efficiency in bulk heterojunction solar cells. We examine the effect of UV-light on the stability of these polymers. The relationship between the polymer chemical structure and the UV-stability of the cells is explored on the one hand, and on the other hand, the effect of additives on their UV-stability: 1,8-diiodooctane against 1-chloronaphthalene in the cells and 1,8-octanedithiol in solution.
View Article and Find Full Text PDFRecently, the advent of non-fullerene acceptors (NFAs) made it possible for organic solar cells (OSCs) to break the 10% efficiency barrier hardly attained by fullerene acceptors (FAs). In the past five years alone, more than hundreds of NFAs with applications in organic photovoltaics (OPVs) have been synthesized, enabling a notable current record efficiency of above 15%. Hence, there is a shift in interest toward the use of NFAs in OPVs.
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