Adsorption and photocatalysis removal of arsenite, arsenate, and hexavalent chromium in water by the carbonized composite of manganese-crosslinked sodium alginate.

The preparation of easily synthesized and cheap composite materials for the efficient removal of toxic oxoanions still remains challenging in sewage treatment. Herein, a new carbonized manganese-crosslinked sodium alginate (Mn/SA-C) was fabricated for the removal of arsenite (As(III)), arsenate (As(V)) and hexavalent chromium (Cr(VI)) in water. The results indicated that the Mn/SA-C pretreated with MnSO solution (Mn/SA-C-S) exhibited a rapid adsorption toward As(III) and As(V) with the removal efficiency of >98% within 10 min, and had a high adsorption capacity toward As(III), As(V), and Cr(VI) with the maximum value of 189.