Recently, transparent ultraviolet (UV) photodetectors have gained wide attention for their giant potential in integrated transparent electronics applications. SnO films as a common candidate for visible-blind transparent ultraviolet photodetectors have attracted increasing attention. In this work, high-performance visible-blind transparent UV photodetectors based on SnO thin film and a SiO passivation layer were successfully synthesized by the sol-gel spin coating method for the first time.
View Article and Find Full Text PDFSearching for a non-rare-earth-based oxide red-emitting phosphor is crucial for phosphor-converted light-emitting diodes (LEDs). In this study, we optimized a blue and UV-light excited SrAlO:Mn phosphor exhibiting red emission peaked at ∼653 nm, which was successfully synthesized by solid-state reaction. The crystal structure, micromorphology, and luminescent properties of SrAlO:Mn phosphors were characterized by X-ray Rietveld refinement, high-resolution transmission electron microscopy, and photoluminescence spectra.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2017
Mn-activated oxide phosphors La(MgTi)O (LMT) with far-red emitting were prepared via a sol-gel route. The structures of samples were determined by X-ray diffraction (XRD) and Reitveld refinement. The occupied sites of Mn (d electronic configuration) in host La(MgTi)O were confirmed by ab initio calculations in which the system has the lower formation energy, stable lattice structure, and strong bonding state as Mn enters into Ti site.
View Article and Find Full Text PDFEu(2+) activated fluorophosphate Ba3GdNa(PO4)3F (BGNPF) with blue and red double-color emitting samples were prepared via a solid-state method in a reductive atmosphere. Their crystal structure and cationic sites were identified in light of X-ray diffraction pattern Rietveld refinement. Three different Ba(2+) sites, coordinated by six O atoms referred to as Ba1, two F and five O atoms as Ba2, and two F and six O atoms as Ba3, were partially substituted by Eu(2+).
View Article and Find Full Text PDFYb(3+)/Er(3+)-ion co-doped Na2Ln2Ti3O10 (Ln = Gd, La) up-conversion (UC) phosphors were successfully synthesized by a sol-gel method, and their crystal structures were characterized by powder X-ray diffraction. Dazzling yellow-greenish light was emitted under the excitation of 980 nm near-infrared (NIR) light, composing green and red emission bands from the (2)H11/2/(4)S3/2→(4)I15/2 and (4)F9/2→(4)I15/2 transitions of Er(3+), respectively. The optimal composition and synthesis parameters were determined according to their UC emission intensity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2013
Ce(3+) and Tb(3+) co-doped Ba2Ln(BO3)2Cl (Ln=Y and Gd) green emitting phosphors were prepared by solid state reaction in reductive atmosphere. The emission and excitation spectra as well as luminescence decays were investigated, showing the occurrence of efficient energy transfer from Ce(3+) to Tb(3+) in this system. The phosphors exhibit both a blue emission from Ce(3+) and a green emission from Tb(3+) under near ultraviolet light excitation with 325-375 nm wavelength.
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