In this study, the biochar obtained from waste cotton fibers was introduced into the Ag-doped g-C3N4/TiO2 hybrid composite through a facile one-step hydrothermal process. The morphology, elemental composition, crystal structure, microstructure, specific surface area, chemical bonding state, energy band structure, and separation efficiency of photoinduced charge carriers of the resultant composite were examined using scanning electron microscope, energy dispersive X-ray spectrometer, X-ray diffractometer, transmission electron microscope, surface area analyzer, X-ray photoelectron spectroscope, Ultraviolet-visible spectrophotometer, ultraviolet photoelectron spectroscope, and photoluminescence spectroscope. The adsorption isotherms, kinetics and thermodynamics of the biochar, Ag-doped g-C3N4/TiO2 and Ag-doped biochar/g-C3N4/TiO2 were evaluated using the model methyl orange dye.
View Article and Find Full Text PDFThe treatment of wastewater containing heavy metals and the utilization of wool waste are very important for the sustainable development of textile mills. In this study, the wool keratin modified magnetite (FeO) powders were fabricated by using wool waste via a co-precipitation technique for removal of Cu ions from aqueous solutions. The morphology, chemical compositions, crystal structure, microstructure, magnetism properties, organic content, and specific surface area of as-fabricated powders were systematically characterized by various techniques including field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), thermogravimetric (TG) analysis, and Brunauer-Emmett-Teller (BET) surface area analyzer.
View Article and Find Full Text PDFIn this study, BiFeO(BFO) nanosheets ground from BFO particles were first incorporated with wool flakes to construct sandwich-like wool-BFO composites using the vibration-assisted ball milling technique in freezing conditions. The wool-BFO composites were then loaded with a thick layer of TiOnanoparticles to prepare the core-shell-structured wool-BFO-TiOcomposites using a hydrothermal synthesis process. The microstructure of the core-shell wool-BFO-TiOcomposites and its photocatalytic applications were systematically examined using a series of characterization methods.
View Article and Find Full Text PDFIn this study, cortical cells resultant from wool fibers were loaded with TiO nanoparticles in a hydrothermal process and were then engineered as organic-nonorganic hybrid composite photocatalysts for both photodegradation of organic dyes and photoreduction of heavy metal ions. The microstructure and photocatalytic properties of TiO modified cortical cells (i.e.
View Article and Find Full Text PDFIn this study, the effects of disperse blue dye-sensitization on the photocatalytic properties of the Ag-N co-doped TiO nanoparticles loaded on polyethylene terephthalate (PET) filaments are investigated under visible light irradiation. The microstructure and photocatalytic properties of the as-synthesized TiO nanocomposites, as well as the as-prepared PET filaments, are systematically characterized. The photocatalytic performance of the PET filaments coated with the Ag-N co-doped TiO nanoparticles sensitized with disperse blue dyes is evaluated via its capacity of photo-degrading methyl orange (MO) dyes under visible light irradiation.
View Article and Find Full Text PDFIn this research, extracellular polymeric substances (EPS), such as EPS and EPS, were successfully extracted from activated and aerobic granular sludge, respectively, and tested as bio-based flame retardant materials. Flax fabric was coated by the biopolymeric substances and its flammability was evaluated based on a vertical burning test defined in US Federal Aviation Regulation. Both EPS and EPS coated flax fabrics achieved the self-extinguishment due to effective char formation.
View Article and Find Full Text PDFGreige cotton (GC) has attracted interest in recent years as an eco-friendly, functional fiber for use in nonwoven topsheet materials. GC imparts favorable fluid management and sensorial properties associated with urinary liquid transport and indices related to comfort in wearable incontinence nonwovens. Nonwoven GC has material surface polarity, an ambient moisture content, and a lipid/polysaccharide matrix that imparts positive fluid mechanic properties applicable to incontinence management topsheet materials.
View Article and Find Full Text PDFA wool-TiO nanoparticle composite material having TiO nanoparticles both infiltrated in the matrix between macrofibrils inside cortical cells of wool fibers and grafted on the fiber surface is obtained in this study, and the wool-nanoparticle composite material is found to have highly photocatalytic activities with an extremely narrow band gap of 2.8 eV. The wool fibers are obtained using three successive technical steps: wool fibers are swollen by using lithium bromide, then saturated with tetrabutyl titanate ethanol solution and subsequently treated in boiling water.
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