Publications by Nina Glebko

Publications by authors named "Nina Glebko"

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Luminescence Thermochromism of Gold(I) Phosphane-Iodide Complexes: A Rule or an Exception?

Nina Glebko Thuy Minh Dau Alexei S Melnikov Elena V Grachova Igor V Solovyev

Chemistry

February 2018

A series of gold(I) iodide complexes 1-11 have been prepared from di-, tri-, and tetraphosphane ligands. Crystallographic studies reveal that the di- (1-7) and tetrametallic (11) compounds feature linearly coordinated gold(I) ions with short aurophilic contacts. Their luminescence behavior is determined by the combined influence of the phosphane properties, metal-metal interaction, and intermolecular lattice-defined interactions.

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