Highly Porous Cationic Polyelectrolytes via Oil-in-Water Concentrated Emulsions: Synthesis and Adsorption Kinetic Study.

This work merges the fields of highly porous polymers (polymerized high internal phase emulsions, polyHIPEs) and synthetic cationic polyelectrolytes and introduces a new approach toward the synthesis of highly porous cationic polyelectrolytes. Cationic polyelectrolytes based on (3-acrylamidopropyl)-trimethylammonium chloride (AMPTMA) were synthesized directly through the oil-in-water HIPEs. The resulting polyelectrolyte-based polyHIPEs are distinguished by the highly porous morphology as well as high concentration and accessibility of the cationic N-quaternized functional groups.