Roadmap on Label-Free Super-Resolution Imaging.

Label-free super-resolution (LFSR) imaging relies on light-scattering processes in nanoscale objects without a need for fluorescent (FL) staining required in super-resolved FL microscopy. The objectives of this Roadmap are to present a comprehensive vision of the developments, the state-of-the-art in this field, and to discuss the resolution boundaries and hurdles which need to be overcome to break the classical diffraction limit of the LFSR imaging. The scope of this Roadmap spans from the advanced interference detection techniques, where the diffraction-limited lateral resolution is combined with unsurpassed axial and temporal resolution, to techniques with true lateral super-resolution capability which are based on understanding resolution as an information science problem, on using novel structured illumination, near-field scanning, and nonlinear optics approaches, and on designing superlenses based on nanoplasmonics, metamaterials, transformation optics, and microsphere-assisted approaches.

Nondiffracting supertoroidal pulses and optical "Kármán vortex streets".

Supertoroidal light pulses, as space-time nonseparable electromagnetic waves, exhibit unique topological properties including skyrmionic configurations, fractal-like singularities, and energy backflow in free space, which however do not survive upon propagation. Here, we introduce the non-diffracting supertoroidal pulses (NDSTPs) with propagation-robust skyrmionic and vortex field configurations that persists over arbitrary propagation distances. Intriguingly, the field structure of NDSTPs has a similarity with the von Kármán vortex street, a pattern of swirling vortices in fluid and gas dynamics with staggered singularities that can stably propagate forward.

Roadmap for Optical Metasurfaces.

Metasurfaces have recently risen to prominence in optical research, providing unique functionalities that can be used for imaging, beam forming, holography, polarimetry, and many more, while keeping device dimensions small. Despite the fact that a vast range of basic metasurface designs has already been thoroughly studied in the literature, the number of metasurface-related papers is still growing at a rapid pace, as metasurface research is now spreading to adjacent fields, including computational imaging, augmented and virtual reality, automotive, display, biosensing, nonlinear, quantum and topological optics, optical computing, and more. At the same time, the ability of metasurfaces to perform optical functions in much more compact optical systems has triggered strong and constantly growing interest from various industries that greatly benefit from the availability of miniaturized, highly functional, and efficient optical components that can be integrated in optoelectronic systems at low cost.

Microwatt Volatile Optical Bistability via Nanomechanical Nonlinearity.

Metastable optically controlled devices (optical flip-flops) are needed in data storage, signal processing, and displays. Although nonvolatile memory relying on phase transitions in chalcogenide glasses has been widely used for optical data storage, beyond that, weak optical nonlinearities have hindered the development of low-power bistable devices. This work reports a new type of volatile optical bistability in a hybrid nano-optomechanical device, comprising a pair of anchored nanowires decorated with plasmonic metamolecules.

Picophotonic localization metrology beyond thermal fluctuations.

Despite recent tremendous progress in optical imaging and metrology, there remains a substantial resolution gap between atomic-scale transmission electron microscopy and optical techniques. Is optical imaging and metrology of nanostructures exhibiting Brownian motion possible with such resolution, beyond thermal fluctuations? Here we report on an experiment in which the average position of a nanowire with a thermal oscillation amplitude of ∼150 pm is resolved in single-shot measurements with subatomic precision of 92 pm, using light at a wavelength of λ = 488 nm, providing an example of such sub-Brownian metrology with ∼λ/5,300 precision. To localize the nanowire, we employ a deep-learning analysis of the scattering of topologically structured light, which is highly sensitive to the nanowire's position.

The Rise of Toroidal Electrodynamics and Spectroscopy.

Toroidal electrodynamics is now massively influencing research in toroidal (Marinov et al. , , 234; Basharin et al. , , 011036; Jeong et al.

Experimental Demonstration of Quantum Overlapping Tomography.

Quantum tomography is one of the major challenges of large-scale quantum information research due to the exponential time complexity. In this Letter, we develop and apply a Bayesian state estimation method to experimentally demonstrate quantum overlapping tomography [Phys. Rev.

Counting and mapping of subwavelength nanoparticles from a single shot scattering pattern.

Particle counting is of critical importance for nanotechnology, environmental monitoring, pharmaceutical, food and semiconductor industries. Here we introduce a super-resolution single-shot optical method for counting and mapping positions of subwavelength particles on a surface. The method is based on the deep learning analysis of the intensity profile of the coherent light scattered on the group of particles.

Toroidal optical transitions in hydrogen-like atoms.

It is commonly believed that electromagnetic spectra of atoms and molecules can be fully described by interactions involving electric and magnetic multipoles. However, it has recently become clear that interactions between light and matter also involve toroidal multipoles-toroidal absorption lines have been observed in electromagnetic metamaterials. Here, we show that a previously unexplored type of spectroscopy of the hitherto largely neglected toroidal dipolar interaction becomes feasible if, apart from the classical × × toroidal dipole density term responsible for the toroidal transitions in metamaterials, the spin-dependent × term (which only occurs in relativistic quantum mechanics) is taken into account.

Ballistic dynamics of flexural thermal movements in a nanomembrane revealed with subatomic resolution.

Flexural oscillations of freestanding films, nanomembranes, and nanowires are attracting growing attention for their importance to the fundamental physical and optical properties and device applications of two-dimensional and nanostructured (meta)materials. Here, we report on the observation of short-time scale ballistic motion in the flexural mode of a nanomembrane cantilever, driven by thermal fluctuation of flexural phonons, including measurements of ballistic velocities and displacements performed with subatomic resolution, using a free electron edge-scattering technique. Within intervals <10 μs, the membrane moves ballistically at a constant velocity, typically ~300 μm/s, while Brownian-like dynamics emerge for longer observation periods.

Quantum Interference of Resonance Fluorescence from Germanium-Vacancy Color Centers in Diamond.

Resonance fluorescence from a quantum emitter is an ideal source to extract indistinguishable photons. By using the cross-polarization to suppress the laser scattering, we observed resonance fluorescence from GeV color centers in diamond at cryogenic temperature. The Fourier-transform-limited line width emission with /2 ∼ 0.

Optical Control of Nanomechanical Brownian Motion Eigenfrequencies in Metamaterials.

Nanomechanical photonic metamaterials provide a wealth of active switching, nonlinear, and enhanced light-matter interaction functionalities by coupling optically and mechanically resonant subsystems. Thermal (Brownian) motion of the nanostructural components of such metamaterials leads to fluctuations in optical properties, which may manifest as noise, but which also present opportunity to characterize performance and thereby optimize design at the level of individual nanomechanical elements. We show that nanomechanical motion in an all-dielectric metamaterial ensemble of silicon-on-silicon-nitride nanowires can be controlled by light at sub-μW/μm intensities.

Deep-Learning-Assisted Focused Ion Beam Nanofabrication.

Focused ion beam (FIB) milling is an important rapid prototyping tool for micro- and nanofabrication and device and materials characterization. It allows for the manufacturing of arbitrary structures in a wide variety of materials, but establishing the process parameters for a given task is a multidimensional optimization challenge, usually addressed through time-consuming, iterative trial-and-error. Here, we show that deep learning from prior experience of manufacturing can predict the postfabrication appearance of structures manufactured by focused ion beam (FIB) milling with >96% accuracy over a range of ion beam parameters, taking account of instrument- and target-specific artifacts.

Supertoroidal light pulses as electromagnetic skyrmions propagating in free space.

Topological complex transient electromagnetic fields give access to nontrivial light-matter interactions and provide additional degrees of freedom for information transfer. An important example of such electromagnetic excitations are space-time non-separable single-cycle pulses of toroidal topology, the exact solutions of Maxwell's equations described by Hellwarth and Nouchi in 1996 and recently observed experimentally. Here we introduce an extended family of electromagnetic excitation, the supertoroidal electromagnetic pulses, in which the Hellwarth-Nouchi pulse is just the simplest member.

Visualization of Subatomic Movements in Nanostructures.

Electron microscopy, scanning probe, and optical super-resolution imaging techniques with nanometric resolution are now routinely available but cannot capture the characteristically fast (MHz-GHz frequency) movements of micro-/nano-objects. Meanwhile, optical interferometric techniques can detect high-frequency picometric displacements but only with diffraction-limited lateral resolution. Here, we introduce a motion visualization technique, based on the spectrally resolved detection of secondary electron emission from moving objects, that combines picometric displacement sensitivity with the nanometric spatial (positional/imaging) resolution of electron microscopy.

Gigahertz Nano-Optomechanical Resonances in a Dielectric SiC-Membrane Metasurface Array.

Optically and vibrationally resonant nanophotonic devices are of particular importance for their ability to enhance optomechanical interactions, with applications in nanometrology, sensing, nano-optical control of light, and optomechanics. Here, the optically resonant excitation and detection of gigahertz vibrational modes are demonstrated in a nanoscale metasurface array fabricated on a suspended SiC membrane. With the design of the main optical and vibrational modes to be those of the individual metamolecules, resonant excitation and detection are achieved by making use of direct mechanisms for optomechanical coupling.

Detection of sub-atomic movement in nanostructures.

Nanoscale objects move fast and oscillate billions of times per second. Such movements occur naturally in the form of thermal (Brownian) motion while stimulated movements underpin the functionality of nano-mechanical sensors and active nano-(electro/opto) mechanical devices. Here we introduce a methodology for detecting such movements, based on the spectral analysis of secondary electron emission from moving nanostructures, that is sensitive to displacements of sub-atomic amplitude.

Unlabeled Far-Field Deeply Subwavelength Topological Microscopy (DSTM).

A nonintrusive far-field optical microscopy resolving structures at the nanometer scale would revolutionize biomedicine and nanotechnology but is not yet available. Here, a new type of microscopy is introduced, which reveals the fine structure of an object through its far-field scattering pattern under illumination with light containing deeply subwavelength singularity features. The object is reconstructed by a neural network trained on a large number of scattering events.

Artificial intelligence for photonics and photonic materials.

Artificial intelligence (AI) is the most important new methodology in scientific research since the adoption of quantum mechanics and it is providing exciting results in numerous fields of science and technology. In this review we summarize research and discuss future opportunities for AI in the domains of photonics, nanophotonics, plasmonics and photonic materials discovery, including metamaterials.

Metamaterial Enhancement of Metal-Halide Perovskite Luminescence.

Metal-halide perovskites are rapidly emerging as solution-processable optical materials for light-emitting applications. Here, we adopt a plasmonic metamaterial approach to enhance photoluminescence emission and extraction of methylammonium lead iodide (MAPbI) thin films based on the Purcell effect. We show that hybridization of the active metal-halide film with resonant nanoscale sized slits carved into a gold film can yield more than 1 order of magnitude enhancement of luminescence intensity and nearly 3-fold reduction of luminescence lifetime corresponding to a Purcell enhancement factor of more than 300.

Phase stabilization of a coherent fiber network by single-photon counting.

Coherent optical fiber networks are extremely sensitive to thermal, mechanical, and acoustic noise, which requires elaborate schemes of phase stabilization with dedicated auxiliary lasers, multiplexers, and photodetectors. This is particularly demanding in quantum networks operating at the single-photon level. Here, we propose a simple method of phase stabilization based on single-photon counting and apply it to quantum fiber networks implementing single-photon interference on a lossless beamsplitter and coherent perfect absorption on a metamaterial absorber.

Resonant nanostructures for highly confined and ultra-sensitive surface phonon-polaritons.

Plasmonics on metal-dielectric interfaces was widely seen as the main route for miniaturization of components and interconnect of photonic circuits. However recently, ultra-confined surface phonon-polaritonics in high-index chalcogenide films of nanometric thickness has emerged as an important alternative to plasmonics. Here, using mid-IR near-field imaging we demonstrate tunable surface phonon-polaritons in CMOS-compatible interfaces of few-nm thick germanium on silicon carbide.

Mechanochromic Reconfigurable Metasurfaces.

The change of optical properties that some usually natural compounds or polymeric materials show upon the application of external stress is named mechanochromism. Herein, an artificial nanomechanical metasurface formed by a subwavelength nanowire array made of molybdenum disulfide, molybdenum oxide, and silicon nitride changes color upon mechanical deformation. The aforementioned deformation induces reversible changes in the optical transmission (relative transmission change of 197% at 654 nm), thus demonstrating a giant mechanochromic effect.