Infochemistry and the Future of Chemical Information Processing.

Nowadays, information processing is based on semiconductor (e.g., silicon) devices.

Photoelectrochemical photocurrent switching effect on a pristine anodized Ti/TiO system as a platform for chemical logic devices.

We report here the effect of the photoelectrochemical photocurrent switching (PEPS) observed on highly-ordered pristine anodized Ti/TiO for the first time. At negative potential bias, blue irradiation gives cathodic photocurrent, whereas anodic photocurrent was observed for ultraviolet irradiation. We believe this phenomenon is due to the electron pathway provided by Ti defect states.

Localization of Ion Concentration Gradients for Logic Operation.

Adjustment of the environmental acidity is a powerful method for fine-tuning the outcome of many chemical processes. Numerous strategies have been developed for the modification of pH in bulk as well as locally. Electrochemical and photochemical processes provide a powerful approach for on-demand generation of ion concentration gradients locally at solid-liquid interfaces.

Coupling pH-Regulated Multilayers with Inorganic Surfaces for Bionic Devices and Infochemistry.

This article summarizes more than 10 years of cooperation with Prof. Helmuth Möhwald. Here we describe how the research moved from light-regulated feedback sustainable systems and control biodevices to the current focus on infochemistry in aqueous solution.

Electrochemical triggering of lipid bilayer lift-off oscillation at the electrode interface.

In situ studies of transmembrane channels often require a model bioinspired artificial lipid bilayer (LB) decoupled from its underlaying support. Obtaining free-standing lipid membranes is still a challenge. In this study, we suggest an electrochemical approach for LB separation from its solid support via hydroquinone oxidation.