Retraction of 'Dual catalysis with magnetic chitosan: direct synthesis of cyclic carbonates from olefins with carbon dioxide using isobutyraldehyde as the sacrificial reductant' by Subodh Kumar , , 2015, , 11860-11866, https://doi.org/10.1039/C5DT01012H.
View Article and Find Full Text PDFA novel catalyst composed of silver nanoparticles grafted on WCN has been prepared by using a facile pH-adjusted method. The material reported in this study presents a non-mineral acid route for the synthesis of the industrially significant monomer adipic acid through the selective oxidation of cyclohexene. Ag has been stabilized in the hydrophobic matrix during the formation of the mesoporous silica material by using aniline as stabilizing agent.
View Article and Find Full Text PDFThin films of imidazolium (Im) ionic liquids with bis(salicylato)borate (BScB) and hexafluorophosphate (PF ) anions were grafted onto copper oxide (CuO) nanorods. Chemical and structural features of ionic-liquid-functionalized CuO (CuO-IL) nanorods were examined by X-ray photoelectron spectroscopy, FTIR spectroscopy, XRD, and high-resolution TEM analyses. The CuO-IL nanorods were demonstrated to be efficient photocatalysts for the splitting of water under visible-light irradiation without using any sacrificial agent.
View Article and Find Full Text PDFChitosan coated magnetic nanoparticles were synthesized and used as a support for the immobilization of the cobalt(II) acetylacetonate complex [Co(acac)2] and quaternary triphenylphosphonium bromide [P(+)Ph3Br(-)] targeting -NH2 and -OH moieties located on the surface of chitosan. The synthesized material was used as a catalyst for one pot direct synthesis of cyclic carbonates from olefins via an oxidative carboxylation approach with carbon dioxide using isobutyraldehyde as the sacrificial reductant and molecular oxygen as the oxidant. After the reaction, the catalyst was recovered by applying an external magnet and reused for several runs without significant loss in catalytic activity and no leaching was observed during this course.
View Article and Find Full Text PDF