From Metallic Lead Films to Perovskite Solar Cells through Lead Conversion with Polyhalide Solutions.

Solutions of methylammonium and formamidinium polyhalides (AX, A = MA, FA, X = I, Br) in isopropanol are introduced as novel versatile precursors for the fabrication of APbX hybrid perovskite thin films via oxidation of metallic Pb. The polyhalide solution with adjustable reactivity is distributed over a metallic Pb layer followed by iodine vapor postprocessing to tune the morphology and composition of the film using only the elements inherently present in the perovskite. This method is easily reproducible in any materials science laboratory with equipment commonly used for perovskite solar cell fabrication and resulted in power conversion efficiencies of 16.