Drinking and wastewater are to be treated for safe human consumption and for keeping surface waters clean. There are multiple water purification procedures, but the use of ion-exchange resins significantly enhances water purification efficiency. This review was targeted on highlighting the concept and classification of polymeric ion-exchange resins as well as pointing out their real-world applications.
View Article and Find Full Text PDFSewage sludge (SS) resulting from wastewater treatment plants (WWTP) is commonly applied worldwide as a fertilizer in agriculture. This can be done following a rigorous analysis of the sewage sludge composition. Due to its toxic potential, heavy metal ion content is one of the key parameters to test when evaluating SS sample usage as fertilizer.
View Article and Find Full Text PDFThis study presents two modified polymers for Cu ion removal from aqueous media. Shredded maize stalk (MC) and a strong-base anionic resin (SAX) were modified with indigo carmine (IC) in order to obtain two different complexing polymers, i.e.
View Article and Find Full Text PDFIn the present study, two chelating resins were prepared and used for simultaneous adsorption of toxic metal ions, i.e., Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb (M).
View Article and Find Full Text PDFIn this paper, two chelate resins prepared by a simple procedure were used for the removal of Cd2+, Ni2+, Cu2+, and Pb2+ (M2+) from aqueous solutions. Amberlite IRA 402 strongly basic anion exchange resin in Cl− form (IRA 402 (Cl−) together with Amberlite XAD7HP acrylic ester co-polymer (XAD7HP) were functionalized with chelating agent Direct red 23 (DR 23). The chelate resins (IRA 402-DR 23 and XAD7HP-DR 23) were obtained in batch mode.
View Article and Find Full Text PDFIn this research, eco-friendly material represented by maize stalk (MS) obtained after acid treatment was employed for simultaneous removal of Cu, Pb, Ni, Cd, Cr and Fe (M) from simulated textile aqueous matrix and tannery wastewater produced by the leather industry. The acid treatment of MS was done with 4 M HCl. The influence of experimental parameters was evaluated in order to optimize the adsorption process for simulated textile matrix.
View Article and Find Full Text PDFThis research had two stages of development: during the first stage, the purpose of the research was to evaluate the adsorption properties of the natural polymer represented by shredded maize stalk (MS) and by Amberlite XAD7HP (XAD7HP) acrylic resin for removal of toxic diazo Acid Blue 113 (AB 113) dye from aqueous solutions. The AB 113 concentration was evaluated spectrometrically at 565 nm. In the second stage, the stability of MS loaded with AB 113 (MS-AB 113) and of XAD7HP loaded with AB 113 (XAD7HP-AB 113) in acidic medium suggests that impregnated materials can be used for selective removal of metal ions (Cr, Zn and Mn).
View Article and Find Full Text PDFDespite Acid Blue 113 (AB 113)'s extensive use and negative environmental impact, very few studies have focused on its efficient and environmentally friendly removal. This research aims the removal of AB 113 from environmental aqueous media and its consequent enzymatic biodegradation. A strongly basic anion exchange resin in Cl form, Amberlite IRA 402 (IRA 402(Cl)) was used for AB 113 adsorption and a laccase was used to further biodegrade it.
View Article and Find Full Text PDFNew research applications involving the use of cellulosic material derived from maize stalk for on-site treatment of leachate were evaluated for specific removal of Cu(II) and Fe(III) from real, highly polluted tailing pond and mine wastewater samples. Two major issues generated by anthropic mining activities were also tackled: wastewater metal content decrease to improve water quality and subsequently metal specific recovery, increasing the economic efficiency of metal production by using a green technology for residual management. Rapid saturation of the maize stalk mass determined in batch studies and the mine pilot experiment led to diminished metal concentrations in the second pilot experiment, where Cu(II) and Pb(II) from synthetic solutions were monitored in order to test biomaterial performances.
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