Spatial and temporal variability of brown carbon in United States: implications for direct radiative effects.

A newly developed dataset from the Interagency Monitoring of PROtected Visual Environments (IMPROVE) observation network, combined with a 3-D chemical transport model, is used to evaluate the spatial and temporal variability of brown carbon (BrC) in the United States. The model with BrC emitted from biomass burning and biofuel emissions agrees with the seasonal and spatial variability of BrC planetary boundary layer (PBL) absorption aerosol optical depth (AAOD) observations within a factor of 2. The model without whitening, the tendency for absorption to decrease with aerosol aging, overestimates the observed BrC PBL AAOD, and does not reflect the measured BrC PBL AAOD spatial variability.

Operational bias correction for PM using the AIRPACT air quality forecast system in the Pacific Northwest.

A bias correction scheme based on a Kalman filter (KF) method has been developed and implemented for the AIRPACT air quality forecast system which operates daily for the Pacific Northwest. The KF method was used to correct hourly rolling 24-h average PM concentrations forecast at each monitoring site within the AIRPACT domain and the corrected forecasts were evaluated using observed daily PM 24-h average concentrations from 2017 to 2018. The evaluation showed that the KF method reduced mean daily bias from approximately -50% to ±6% on a monthly averaged basis, and the corrected results also exhibited much smaller mean absolute errors typically less than 20%.