Int J Biol Macromol
January 2024
This paper explores the application of cross-linked cellulose beads as a sustainable and cost-effective support for the ZnO/SnO/carbon xerogel hybrid photocatalyst. The application of the developed photocatalytic beads, named CB-Cat, was directed at a simultaneous adsorption/photocatalysis process, which was carried out under simulated sunlight. The characterization of the CB-Cat indicated a good dispersion of the photocatalyst of choice throughout the cellulose matrix, confirming its incorporation into the cellulose beads.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2023
This paper proposes the study of a solar-based photocatalytic ozonation process for the degradation of salicylic acid (SA) using a novel S-scheme ZnO/CuO/CuO/carbon xerogel photocatalyst. The incorporation of CuO and CuO aims to enhance charge mobility through the formation of p-n heterojunctions with ZnO, whereas the carbon xerogel (XC) was selected due to its eco-friendly nature, capacity to stabilize S-scheme heterojunctions as a solid-state electron mediator, and ability to function as a reducing agent under high temperatures. The characterization of the composites demonstrates that the presence of the XC during the calcination step led to the reduction of a fraction of the CuO into CuO, forming a ternary semiconductor heterojunction system.
View Article and Find Full Text PDFThis work proposed new black-wattle tannin/kraft lignin HPO-activated carbon xerogels as sustainable and efficient adsorbents. The precursors were chosen based on their eco-friendly and cost-effective nature, aiming to achieve adsorbents with high adsorption capacities. Carbon xerogels were synthesized through polycondensation with formaldehyde and alkaline catalyst in a simple one-pot procedure.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2023
Considering the ever-increasing need for efficient wastewater treatment, this study focused on the development of new kraft lignin-based carbon xerogel/zinc oxide (XCL/ZnO w) photocatalysts. The inclusion of the carbon xerogel is expected to cause an improvement in charge transfer throughout the photoactivation process, consequently enhancing its overall photocatalytic efficiency. Characterization shows that the materials developed are composed of both zinc oxide and carbon xerogel.
View Article and Find Full Text PDFThis study is focused on the evaluation of the Rhodamine B photodegradation using ZnO/carbon xerogel composite as a photocatalyst, in order to enhance the photocatalytic process efficiency under visible light. The proposed synthesis employs tannin as a precursor for the carbon xerogel, which enhances the economic and environmental aspect of the composite. The synthesized materials have the hexagonal structure of the zinc oxide (wurtzite), which is homogeneously distributed on the carbonaceous matrix.
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