The potential release in the environment and biological effects of chemicals like additives and non-intentionally added substances present in conventional plastics and bioplastics is an issue that could occur if these materials are not properly disposed of. Herein, seven leachates of biobased and biodegradable plastics made of polylactic acid (PLA), polybutylene succinate (PBS)/PLA blends, and starch-based blends (SB) were characterized and compared for the inorganic and organic additives present in the source materials. The main inorganic elements found in the leachates were Na, Mg, K, and Ca (0.
View Article and Find Full Text PDFArsenic (As) in groundwater from natural and anthropogenic sources is one of the most common pollutants worldwide affecting people and ecosystems. A large dataset from >3600 wells is employed to spatially simulate the depth-averaged As concentration in phreatic and confined aquifers of the Padana Plain (Northern Italy). Results of in-depth geostatistical analysis via PCA and simulations within a Monte Carlo framework allow the understanding of the variability of As concentrations within the aquifers.
View Article and Find Full Text PDFNanocrystalline calcium carbonate (CaCO) and amorphous CaCO (ACC) are materials of increasing technological interest. Nowadays, they are mainly synthetically produced by wet reactions using CaCO reagents in the presence of stabilizers. However, it has recently been discovered that ACC can be produced by ball milling calcite.
View Article and Find Full Text PDFRemediation of residually contaminated soils remains a widespread problem. Biochar can immobilize polycyclic aromatic hydrocarbons (PAH). However, studies on its ability to immobilize PAH and N, S, and O substituted PAH (hetero-PAH) in real soils, and benchmarking with commercial activated carbon are missing.
View Article and Find Full Text PDFThe circular economy approach imposes the complete recovery of components, materials and energy from waste. Many active compounds with biomedical and nutraceutical applications can be extracted by Fish Waste (FW), but few are the operating industrial plants. Quantification and mapping of the potential FW availability along the entire fish value-chain is crucial in fostering its actual valorisation.
View Article and Find Full Text PDFCoastal lagoons are complex environments threatened by natural and anthropogenic stressors. Here, we tested the effectiveness of combining physical, geochemical and chemical measurements with biomarker data obtained in field-exposed marine mussels (Mytilus galloprovincialis) as a biomonitoring strategy for a highly pressured lagoon (Pialassa Baiona, Ravenna, Italy). Data showed a spatial trend of sediment contamination by Hg, Pt, Au, Ag, Mo, Re, Cd, Pd and Zn.
View Article and Find Full Text PDFThe ability of microalgae to sequester carbon and at the same time synthesise valuable compounds with potential applications in nutraceutical, pharmaceutical and cosmetic industries makes them attractive for commercial deployment, especially in view of a blue bioeconomy. Among microalgae, the diatom Phaeodactylum tricornutum is considered as an important potential source of omega-3 polyunsaturated fatty acids, such as eicosapentanoic acid, an essential polyunsaturated fatty acid with anti-inflammatory and antimicrobial properties. The aim of this study was to perform the Life Cycle Assessment of the cultivation of P.
View Article and Find Full Text PDFWithin Circular Economy principles, this paper analyses and estimates exploitable marine residues, such as fish waste and stranded debris in beaches and their potential valorisation scenarios. The Emilia-Romagna Region (Italy) has been chosen as a case study. Based on the sold fish, about 200 Mg/year of fish waste are produced at the five major fish markets of the Region.
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