Treatment of iron(II) chloride or iron(II) bromide with 2 equiv of sodium quinaldate (qn = quinaldate or C(10)H(6)NO(2)(-)) yields the coordinatively unsaturated mononuclear iron(II) quinaldate complexes Na[Fe(II)(qn)(2)Cl].DMF and Na[Fe(II)(qn)(2)Br].DMF (DMF = N,N-dimethylformamide), respectively.
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