Selective thermal emission in a useful range of energies from a material operating at high temperatures is required for effective solar thermophotovoltaic energy conversion. Three-dimensional metallic photonic crystals can exhibit spectral emissivity that is modified compared with the emissivity of unstructured metals, resulting in an emission spectrum useful for solar thermophotovoltaics. However, retention of the three-dimensional mesostructure at high temperatures remains a significant challenge.
View Article and Find Full Text PDFDielectric/metal/dielectric (DMD) electrodes have the potential to significantly increase the absorption efficiency and photocurrent in flexible organic solar cells. We demonstrate that this enhancement is attributed to a broadband cavity resonance. Silver-based semitransparent DMD electrodes with sheet resistances below 10 ohm/sq.
View Article and Find Full Text PDFThe control of thermal radiation is of great current importance for applications such as energy conversions and radiative cooling. Here we show theoretically that the thermal emission of a finite-size blackbody emitter can be enhanced in a thermal extraction scheme, where one places the emitter in optical contact with an extraction device consisting of a transparent object, as long as both the emitter and the extraction device have an internal density of state higher than vacuum, and the extraction device has an area larger than the emitter and moreover has a geometry that enables light extraction. As an experimental demonstration of the thermal extraction scheme, we observe a four-fold enhancement of the far-field thermal emission of a carbon-black emitter having an emissivity of 0.
View Article and Find Full Text PDFSpectral control of the emissivity of surfaces is essential for efficient conversion of solar radiation into heat. We investigated surfaces consisting of sub-wavelength V-groove gratings coated with aperiodic metal-dielectric stacks. The spectral behavior of the coated gratings was modeled using rigorous coupled-wave analysis (RCWA).
View Article and Find Full Text PDFSpectral control of the emissivity of surfaces is essential in applications such as solar thermal and thermophotovoltaic energy conversion in order to achieve the highest conversion efficiencies possible. We investigated the spectral performance of planar aperiodic metal-dielectric multilayer coatings for these applications. The response of the coatings was optimized for a target operational temperature using needle-optimization based on a transfer matrix approach.
View Article and Find Full Text PDF