Modeling nematic phase main-chain liquid crystal elastomer synthesis, mechanics, and thermal actuation coarse-grained molecular dynamics.

This paper presents a coarse-grained molecular dynamics simulation study of the synthesis, mechanics, and thermal actuation of nematic phase main-chain liquid crystal elastomers (LCEs), a type of soft, temperature-responsive, polymeric actuating material. The simulations herein model the crosslinking, mechanical stretching, and additional crosslinking synthesis process, following which, the simulated LCE exhibits a direction-dependent thermal actuation and mechanical response. The thermal actuation response shows good qualitative agreement with experimental results, including the variation of a global order parameter that describes the orientation of the mesogen domains comprising the LCE.

In situ measurement of damage evolution in shocked magnesium as a function of microstructure.

Accurate modeling and prediction of damage induced by dynamic loading in materials have long proved to be a difficult task. Examination of postmortem recovered samples cannot capture the time-dependent evolution of void nucleation and growth, and attempts at analytical models are hindered by the necessity to make simplifying assumptions, because of the lack of high-resolution, in situ, time-resolved experimental data. We use absorption contrast imaging to directly image the time evolution of spall damage in metals at ∼1.

Strain topological metamaterials and revealing hidden topology in higher-order coordinates.

Topological physics has revolutionized materials science, introducing topological phases of matter in diverse settings ranging from quantum to photonic and phononic systems. Herein, we present a family of topological systems, which we term "strain topological metamaterials", whose topological properties are hidden and unveiled only under higher-order (strain) coordinate transformations. We firstly show that the canonical mass dimer, a model that can describe various settings such as electrical circuits and optics, among others, belongs to this family where strain coordinates reveal a topological nontriviality for the edge states at free boundaries.

Synthetically non-Hermitian nonlinear wave-like behavior in a topological mechanical metamaterial.

Topological mechanical metamaterials have enabled new ways to control stress and deformation propagation. Exemplified by Maxwell lattices, they have been studied extensively using a linearized formalism. Herein, we study a two-dimensional topological Maxwell lattice by exploring its large deformation quasi-static response using geometric numerical simulations and experiments.

Dynamic compression of soft layered materials yields tunable and spatiotemporally evolving surface patterns.

Soft layered systems buckling to form surface patterns has been widely studied under quasistatic loading. Here, we study the dynamic formation of wrinkles in a stiff-film-on-viscoelastic-substrate system as a function of impact velocity. We observe a spatiotemporally varying range of wavelengths, which display impactor velocity dependence and exceed the range exhibited under quasistatic loading.

Microscale concert hall acoustics to produce uniform ultrasound stimulation for targeted sonogenetics in hsTRPA1-transfected cells.

The field of ultrasound neuromodulation has rapidly developed over the past decade, a consequence of the discovery of strain-sensitive structures in the membrane and organelles of cells extending into the brain, heart, and other organs. Notably, clinical trials are underway for treating epilepsy using focused ultrasound to elicit an organized local electrical response. A key limitation to this approach is the formation of standing waves within the skull.

Temperature-controlled spatiotemporally modulated phononic crystal for achieving nonreciprocal acoustic wave propagation.

We computationally investigate a method for spatiotemporally modulating a material's elastic properties, leveraging thermal dependence of elastic moduli, with the goal of inducing nonreciprocal propagation of acoustic waves. Acoustic wave propagation in an aluminum thin film subjected to spatiotemporal boundary heating from one side and constant cooling from the other side was simulated via the finite element method. Material property modulation patterns induced by the asymmetric boundary heating are found to be non-homogenous with depth.

Mechanoactivation of Color and Autonomous Shape Change in 3D-Printed Ionic Polymer Networks.

Stimuli-responsive materials can enhance the field of three-dimensional (3D) printing by generating objects that change shape in response to external cues. While temperature and pH are common inputs for initiating a response in a 3D-printed object, there are few examples of using a mechanical input to afford a response. Herein, we report a suite of mechanochromic ionic liquid gel inks that can be used to fabricate 3D-printed objects that use a single mechanoactivation event to elicit both a mechanochromic response and an autonomous shape change.

Longitudinal eigenvibration of multilayer colloidal crystals and the effect of nanoscale contact bridges.

Longitudinal contact-based vibrations of colloidal crystals with a controlled layer thickness are studied. These crystals consist of 390 nm diameter polystyrene spheres arranged into close packed, ordered lattices with a thickness of one to twelve layers. Using laser ultrasonics, eigenmodes of the crystals that have out-of-plane motion are excited.

Mechanochromic Stretchable Electronics.

Soft and stretchable electronics are promising for a variety of applications such as wearable electronics, human-machine interfaces, and soft robotics. These devices, which are often encased in elastomeric materials, maintain or adjust their functionality during deformation, but can fail catastrophically if extended too far. Here, we report new functional composites in which stretchable electronic properties are coupled to molecular mechanochromic function, enabling at-a-glance visual cues that inform user control.

Laser-Induced Spallation of Microsphere Monolayers.

The detachment of a semiordered monolayer of polystyrene microspheres adhered to an aluminum-coated glass substrate is studied using a laser-induced spallation technique. The microsphere-substrate adhesion force is estimated from substrate surface displacement measurements obtained using optical interferometry, and a rigid-body model that accounts for the inertia of the microspheres. The estimated adhesion force is compared with estimates obtained using an adhesive contact model together with interferometric measurements of the out-of-plane microsphere contact resonance, and with estimated work of adhesion values for the polystyrene-aluminum interface.

Nonlinear waves in disordered diatomic granular chains.

We investigate the propagation and scattering of highly nonlinear waves in disordered granular chains composed of diatomic (two-mass) units of spheres that interact via Hertzian contact. Using ideas from statistical mechanics, we consider each diatomic unit to be a "spin," so that a granular chain can be viewed as a spin chain composed of units that are each oriented in one of two possible ways. Experiments and numerical simulations both reveal the existence of two different mechanisms of wave propagation: in low-disorder chains, we observe the propagation of a solitary pulse with exponentially decaying amplitude.