Observation of Charge Generation via Photoinduced Stark Effect in Mixed-Cation Lead Bromide Perovskite Thin Films.

Extensive transient absorption studies on hybrid organic-inorganic lead halide perovskites have elucidated many optical properties important for their device performance. Despite the enormous progress, the derivative shaped photoinduced absorption feature in transient spectra that is above the bandgap has many explanations, including the photoinduced Stark effect, where the bandgap is blue shifted due to a local electric field generated by charges. In this work, we employ broad band transient absorption and two-dimensional electronic spectroscopy (2DES) to examine the early transient events after photoexcitation of [CH(NH)]CsPbBr (FACsPbBr).

Mixed-Halide Perovskites with Stabilized Bandgaps.

One merit of organic-inorganic hybrid perovskites is their tunable bandgap by adjusting the halide stoichiometry, an aspect critical to their application in tandem solar cells, wavelength-tunable light emitting diodes (LEDs), and lasers. However, the phase separation of mixed-halide perovskites caused by light or applied bias results in undesirable recombination at iodide-rich domains, meaning open-circuit voltage (V) pinning in solar cells and infrared emission in LEDs. Here, we report an approach to suppress halide redistribution by self-assembled long-chain organic ammonium capping layers at nanometer-sized grain surfaces.

In Situ Preparation of Metal Halide Perovskite Nanocrystal Thin Films for Improved Light-Emitting Devices.

Hybrid organic-inorganic halide perovskite semiconductors are attractive candidates for optoelectronic applications, such as photovoltaics, light-emitting diodes, and lasers. Perovskite nanocrystals are of particular interest, where electrons and holes can be confined spatially, promoting radiative recombination. However, nanocrystalline films based on traditional colloidal nanocrystal synthesis strategies suffer from the use of long insulating ligands, low colloidal nanocrystal concentration, and significant aggregation during film formation.