Alkali-thermal activated persulfate treatment of tetrabromobisphenol A in soil: Parameter optimization, mechanism, degradation pathway and toxicity evaluation.

The continued accumulation of halogenated organic pollutants in soil posed a potential threat to ecosystems and human health. In this study, tetrabromobisphenol A (TBBPA) was used as a typical representative of halogenated organic pollutants in soil, for alkali-thermal activated persulfate (PS) treatment. The results of response surface methodology (RSM) showed a optimal debromination efficiency of TBBPA was 88.

A carbothermic hybrid synthesized using waste halogenated plastic in sub/supercritical CO and its application for lithium recovery.

Facile fabrication of porous carbon materials from waste halogenated plastic is highly attractive but frequently hampered due to potential release of halogenated organic pollutants. In this study, a novel type of carbon hybrid was tentatively synthesized from a real-world halogenated plastic as an inexpensive carbon source by sub/supercritical carbon dioxide carbonization technique. It was found that halogen-free carbon carrier was advantageously synthesized through carbonization of halogenated plastic without using catalysts due to zip depolymerization, random chain cracking and free radical reactions induced by sub/supercritical carbon dioxide technique.

Alkali-catalyzed hydrothermal oxidation treatment of triclosan in soil: Mechanism, degradation pathway and toxicity evaluation.

The continuous accumulation of chlorinated organic pollutants in soil poses a potential threat to ecosystems and human health alike. Alkali-catalyzed hydrothermal oxidation (HTO) can successfully remove chlorinated organic pollutants from water, but it is rarely applied to soil remediation. In this work, we assessed this technique to degrade and detoxify triclosan (TCS) in soil and we determined the underlying mechanisms.

Activation or sequestration of heavy metals during hydrothermal process of swine manure: Interactions among metal species and particulates.

Whether the heavy metals in solid biomass is activated or sequestrated during hydrothermal process (HTP) is still debated. Herein, the speciation of light and heavy metals during HTP of swine manure (SM) was investigated to reveal the interactions among these metal species and specific particulates. With increasing temperature, most of exchangeable species and that bound to carbonates were released to liquid phase via ion exchange and acid dissolution.

Application of sequential extraction analysis to Pb(II) recovery by zerovalent iron-based particles.

Zerovalent iron (ZVI) is an environmental-friendly reactive reagent for recovering heavy metals. However, the detailed recovery mechanism remains unclear due to a lack of quantitative analysis of recovery products. Herein, microscale ZVI, nanoscale ZVI and Ni/Fe nanoparticles were used to recover Pb(II) in aqueous solution and a sequential extraction procedure (SEP) was applied to determine the formed lead species quantitatively.

Electrokinetic removal of Cu and Zn in anaerobic digestate: interrelation between metal speciation and electrokinetic treatments.

In recent years, a potential controversy has arisen that whether the metal speciation in solid matrix determined its electrokinetic (EK) removal efficiency or by contrast. In present study, Cu and Zn in anaerobic digestate were selected as candidates to investigate the relation between the species of metal and EK treatment. The obtained results show that the removal efficiency for each fraction decreased in the order as follows: exchangeable ≥ bound to carbonates > bound to Fe-Mn oxides>bound to organic matters >> residual.

Nutrition potential of biogas residues as organic fertilizer regarding the speciation and leachability of inorganic metal elements.

Biogas residues (BRs) are prospective organic fertilizer sources for agricultural cultivation. Besides N and P, however, other inorganic metal elements, such as K, Fe, Cu, Zn and so on, also affect the nutritional level of BRs significantly. In this study, a sequential extraction procedure (SEP) combined with a toxicity characteristic leaching procedure (TCLP) was conducted to investigate the speciation and leachability of metal components in BRs.

Sequential extraction of anaerobic digestate sludge for the determination of partitioning of heavy metals.

In China, agricultural use of anaerobic digestate sludge is considered a concern due to high heavy metal content of the sludge. In this study, sequential extraction procedure (SEP) was conducted to determine metal speciation which affects release and mobility of metal significantly. The results of SEP showed that each heavy metal possessed different distribution characteristics.