Photon-assisted ultrafast electron-hole plasma expansion in direct band semiconductors.

Time-resolved terahertz spectroscopy is used to investigate formation and ultrafast long-distance propagation of electron-hole plasma in strongly photoexcited GaAs and InP. The observed phenomena involve fundamental interactions of electron-hole system with light, which manifest themselves in two different regimes: a coherent one with the plasma propagation speeds up to /10 (in GaAs at 20 K) and an incoherent one reaching up to /25 (in InP at 20 K), both over a macroscopic distance >100 μm. We explore a broad range of experimental conditions by investigating the two materials, by tuning their band gap with temperature and by controlling the interaction strength with the optical pump fluence.

Ultrafast Long-Distance Electron-Hole Plasma Expansion in GaAs Mediated by Stimulated Emission and Reabsorption of Photons.

Electron-hole plasma expansion with velocities exceeding c/50 and lasting over 10 ps at 300 K was evidenced by time-resolved terahertz spectroscopy. This regime, in which the carriers are driven over >30  μm is governed by stimulated emission due to low-energy electron-hole pair recombination and reabsorption of the emitted photons outside the plasma volume. At low temperatures a speed of c/10 was observed in the regime where the excitation pulse spectrally overlaps with emitted photons, leading to strong coherent light-matter interaction and optical soliton propagation effects.

Terahertz charge transport dynamics in 3D graphene networks with localization and band regimes.

Terahertz steady-state and time-resolved conductivity and permittivity spectra were measured in 3D graphene networks assembled in free-standing covalently cross-linked graphene aerogels. Investigation of a transition between reduced-graphene oxide and graphene controlled by means of high-temperature annealing allowed us to elucidate the role of defects in the charge carrier transport in the materials. The THz spectra reveal increasing conductivity and decreasing permittivity with frequency.

Correlation of D-dimer and Outcomes in COVID-19 Patients.

Background: The coronavirus disease 2019 (COVID-19) global pandemic has impacted daily life and medical practices around the world. Hospitals are continually making observations about this unique population as it relates to laboratory data and outcomes. Plasma D-dimer levels have been shown to be promising as a prognostic factor for outcomes in COVID-19 patients.

MUlticenter STudy of tissue plasminogen activator (alteplase) use in COVID-19 severe respiratory failure (MUST COVID): A retrospective cohort study.

Background: Few therapies exist to treat severe COVID-19 respiratory failure once it develops. Given known diffuse pulmonary microthrombi on autopsy studies of COVID-19 patients, we hypothesized that tissue plasminogen activator (tPA) may improve pulmonary function in COVID-19 respiratory failure.

Methods: A multicenter, retrospective, observational study of patients with confirmed COVID-19 and severe respiratory failure who received systemic tPA (alteplase) was performed.

Wittmann Patch : Superior Closure for the Open Abdomen.

Introduction: Damage control laparotomy (DCL) is a life-saving surgical technique, but the resultant open abdomen (OA) carries serious morbidity/mortality. Many methods are utilized to manage OAs, but discrepancy exists in distinguishing closure from coverage techniques. We observed a difference in our DCL patient outcomes managed with the Wittmann Patch (WP) closure device versus the more popular ABThera (AB) coverage device.

Does Human Amnion Membrane Prevent Postoperative Abdominal Adhesions?

Background: Adhesions are bands of tissue that form postoperatively after intra-abdominal surgery. Adhesions cause significant morbidity and despite ongoing research no agent or method has been shown to completely prevent adhesions. Human amnion-derived matrix is a complex tissue matrix derived from human placenta and has been used in other areas of surgery to promote healing and decrease scar tissue formation.

Early outcomes with utilization of tissue plasminogen activator in COVID-19-associated respiratory distress: A series of five cases.

Background: Coronavirus patients demonstrate varying degrees of respiratory insufficiency; many will progress to respiratory failure with a severe version of acute respiratory distress syndrome refractory to traditional supportive strategies. Providers must consider alternative therapies to deter or prevent the cascade of decompensation to fulminant respiratory failure.

Methods: This is a case-series of five COVID-19 positive patients who demonstrated severe hypoxemia, declining respiratory performance, and escalating oxygen requirements.

Effect of hydrogen chloride etching on carrier recombination processes of indium phosphide nanowires.

Introduction of in situ HCl etching to an epitaxial growth process has been shown to suppress radial growth and improve the morphology and optical properties of nanowires. In this paper, we investigate the dynamics of photo-generated charge carriers in a series of indium phosphide nanowires grown with varied HCl fluxes. Time resolved photo-induced luminescence, transient absorption and time resolved terahertz spectroscopy were employed to investigate charge trapping and recombination processes in the nanowires.

Time-resolved terahertz spectroscopy reveals the influence of charged sensitizing quantum dots on the electron dynamics in ZnO.

Photoinitiated charge carrier dynamics in ZnO nanoparticles sensitized by CdSe quantum dots is studied using transient absorption spectroscopy and time-resolved terahertz spectroscopy. The evolution of the transient spectra shows that electron injection occurs in a two-step process, where the formation of a charge transfer state (occurring in several picoseconds) is followed by its dissociation within tens of picoseconds. The photoconductivity of electrons injected into the ZnO nanoparticles is lower than that of charges photogenerated directly in ZnO.

Bulk magnetic terahertz metamaterials based on dielectric microspheres.

Rigid metamaterials were prepared by embedding TiO microspheres into polyethylene. These structures exhibit a series of Mie resonances where the lowest-frequency one is associated with a strong dispersion in the effective magnetic permeability. Using time-domain terahertz spectroscopy, we experimentally demonstrated the magnetic nature of the observed resonance.

Charge transport in thin layer Na x CoO2 (x ∼ 0.63) studied by terahertz spectroscopy.

Charge transport in Na0.63CoO2 thin film deposited by a spin-coating method was investigated experimentally by time-domain terahertz spectroscopy and theoretically using Monte Carlo calculations of charge response in nano-structured materials. The dominating type of transport mechanism over the entire investigated range of temperatures (20-300 K) is a metallic-like conductivity of charges partly confined in constituting nano-sized grains.

Self-referenced ultra-broadband transient terahertz spectroscopy using air-photonics.

Terahertz (THz) air-photonics employs nonlinear interactions of ultrashort laser pulses in air to generate and detect THz pulses. As air is virtually non-dispersive, the optical-THz phase matching condition is automatically met, thus permitting the generation and detection of ultra-broadband THz pulses covering the entire THz spectral range without any gaps. Air-photonics naturally offers unique opportunities for ultra-broadband transient THz spectroscopy, yet many critical challenges inherent to this technique must first be resolved.

Long-range and high-speed electronic spin-transport at a GaAs/AlGaAs semiconductor interface.

Spin-valves or spin-transistors in magnetic memories and logic elements are examples of structures whose functionality depends crucially on the length and time-scales at which spin-information is transferred through the device. In our work we employ spatially resolved optical pump-and-probe technique to investigate these fundamental spin-transport parameters in a model semiconductor system. We demonstrate that in an undoped GaAs/AlGaAs layer, spins are detected at distances reaching more than ten microns at times as short as nanoseconds.

Transition between metamaterial and photonic-crystal behavior in arrays of dielectric rods.

Using finite-difference time-domain simulations, we study the interactions of electromagnetic radiation with a square array of dielectric rods parallel to the electric vector. We observe the electric and magnetic Mie resonances which induce intervals of negative effective permittivity and permeability and which contribute to the formation of the photonic band gaps. Owing to the interplay of these phenomena, a narrow spectral range with a negative refractive index can occur.

Monte Carlo simulations of thin hydrocarbon films: composition heterogeneity and structure at the solid-liquid and liquid-vapor interfaces.

The structural properties of 10 nm thick lubricant films consisting of binary and ternary n-alkane mixtures (8 ≤ n ≤ 12) adsorbed on a structureless metal substrate were studied for several temperatures and compositions using Monte Carlo simulations. Configurational-bias Monte Carlo identity switch moves are essential to sample the spatial distribution in these mixtures. Longer alkanes are found to preferentially adsorb onto the substrate while shorter alkanes are enriched at the liquid-vapor interface.

Electron and Hole Contributions to the Terahertz Photoconductivity of a Conjugated Polymer:Fullerene Blend Identified.

Time-resolved terahertz spectroscopy was employed for the investigation of charge-transport dynamics in benzothiadiazolo-dithiophene polyfluorene ([2,7-(9,9-dioctyl-fluorene)-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]) (APFO-3) polymers with various chain lengths and in its monomer form, all blended with an electron acceptor ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM). Upon photoexcitation, charged polaron pairs are created, negative charges are transferred to fullerenes, while positive polarons remain on polymers/monomers. Vastly different hole mobility in polymer and monomer blends allows us to distinguish the hole and electron contributions to the carrier mobility.

Charge carrier mobility in poly[methyl(phenyl)silylene] studied by time-resolved terahertz spectroscopy and molecular modelling.

Time-resolved terahertz spectroscopy and combination of quantum chemistry modeling and molecular dynamics simulations were used for the determination of charge carrier mobility in poly[methyl(phenyl)silylene]. Using time-resolved THz spectroscopy we established the on-chain charge carrier drift mobility in PMPSi as 0.02 cm(2) V(-1) s(-1).

Influence of the electron-cation interaction on electron mobility in dye-sensitized ZnO and TiO2 nanocrystals: a study using ultrafast terahertz spectroscopy.

Charge transport and recombination in nanostructured semiconductors are poorly understood key processes in dye-sensitized solar cells. We have employed time-resolved spectroscopies in the terahertz and visible spectral regions supplemented with Monte Carlo simulations to obtain unique information on these processes. Our results show that charge transport in the active solar cell material can be very different from that in nonsensitized semiconductors, due to strong electrostatic interaction between injected electrons and dye cations at the surface of the semiconductor nanoparticle.

Gouy shift correction for highly accurate refractive index retrieval in time-domain terahertz spectroscopy.

Terahertz spectroscopic measurements are usually performed in focused beam geometry while the standard routine for the retrieval of the sample refractive index assumes plane-wave approximation. In this paper we propose a model for the transmission function which accounts for spatially limited Gaussian terahertz beams. We demonstrate experimentally its validity and applicability for an accurate extraction of the refractive index from experimental data.

Broadband dielectric terahertz metamaterials with negative permeability.

We present a design of dielectric metamaterials exhibiting a broad range of negative effective permeability in the terahertz spectral region. The investigated structures consist of an array of high-permittivity rods that exhibit a series of Mie resonances giving rise to the effective magnetic response. The spectral positions of resonances depend on the geometrical parameters of the rods and on their permittivity, which define the resonant confinement of the electromagnetic field within the rods.