Task-Based Attentional Control: The Role of Anxiety and Age.

Objective: Attentional Control Theory (ACT) posits that anxiety impacts cognitive functioning through interference in working memory and processing efficiency, resulting in performance deficits in set-shifting and inhibition. Few studies have examined the effects of anxiety on set-shifting and inhibition in clinical samples or how these relationships might be affected by age. The current study tested whether increased age, elevated anxiety, and their interaction were associated with reduced performance on measures of set-shifting and inhibition.

Advancements in mapping areas suitable for wetland habitats across the conterminous United States.

Wetland habitats provide critical ecosystem services to the surrounding landscape, including nutrient and pollutant retention, flood mitigation, and carbon storage. Wetland connectivity to water bodies and related ecosystems is critical in habitat sustainability, but there are limited resources for landscape-level wetland planning. Considering the network connectivity of an ecosystem type can derive different benefits to the natural and built environment, as well as human health.

Simultaneous Surface-Enhanced Raman Scattering with a Kerr Gate for Fluorescence Suppression.

The combination of surface-enhanced and Kerr-gated Raman spectroscopy for the enhancement of the Raman signal and suppression of fluorescence is reported. Surface-enhanced Raman scattering (SERS)-active gold substrates were demonstrated for the expansion of the surface generality of optical Kerr-gated Raman spectroscopy, broadening its applicability to the study of analytes that show a weak Raman signal in highly fluorescent media under (pre)resonant conditions. This approach is highlighted by the well-defined spectra of rhodamine 6G, Nile red, and Nile blue.

Our national nutrient reduction needs: Applying a conservation prioritization framework to US agricultural lands.

Targeted conservation approaches seek to focus resources on areas where they can deliver the greatest benefits and are recognized as key to reducing nonpoint source nutrients from agricultural landscapes into sensitive receiving waters. Moreover, there is growing recognition of the importance and complementarity of in-field and edge-of-field conservation for reaching nutrient reduction goals. Here we provide a generic prioritization that can help with spatial targeting and applied it across the conterminous US (CONUS).

Using cellular device location data to estimate visitation to public lands: Comparing device location data to U.S. National Park Service's visitor use statistics.

Understanding human use of public lands is essential for management of natural and cultural resources. However, compiling consistently reliable visitation data across large spatial and temporal scales and across different land managing entities is challenging. Cellular device locations have been demonstrated as a source to map human activity patterns and may offer a viable solution to overcome some of the challenges that traditional on-the-ground visitation counts face on public lands.

Association of Redlining and Natural Environment with Depressive Symptoms in Women in the Sister Study.

Background: Improving mental health is recognized as an important factor for achieving global development goals. Despite strong evidence that neighborhood greenery promotes better mental health, there are environmental justice concerns over the distribution of neighborhood greenery. Underlying these concerns are present-day consequences of historical discriminatory financial investment practices, such as redlining which was established by the U.

Where forest may not return in the western United States.

Droughts that are hotter, more frequent, and last longer; pest outbreaks that are more extensive and more common; and fires that are more frequent, more extensive, and perhaps more severe have raised concern that forests in the western United States may not return once disturbed by one or more of these agents. Numerous field-based studies have been undertaken to better understand forest response to these changing disturbance regimes. Meta-analyses of these studies provide broad guidelines on the biotic and abiotic factors that hinder forest recovery, but study-to-study differences in methods and objectives do not support estimation of the total extent of potentially impaired forest succession.

Improving intelligent dasymetric mapping population density estimates at 30 m resolution for the conterminous United States by excluding uninhabited areas.

Population change impacts almost every aspect of global change from land use, to greenhouse gas emissions, to biodiversity conservation, to the spread of disease. Data on spatial patterns of population density help us understand patterns and drivers of human settlement and can help us quantify the exposure we face to natural disasters, pollution, and infectious disease. Human populations are typically recorded by national or regional units that can vary in shape and size.

Hiring intentions and remuneration of veterinary practitioners in western Canada.

All private veterinary practices in western Canada (N = 1333) were surveyed during the SARS-CoV-2 pandemic (January to November 2020) to generate data on the demographics of the profession, and to quantify past and present hiring intentions (demand) as well as remuneration for veterinary associates. The response rate was 39.5% (526/1333), 186 of which had hired at least one full- (FT) or part-time (PT) associate within the 12-month period preceding the completion of the survey.

Lithium Insertion into Graphitic Carbon Observed via Operando Kerr-Gated Raman Spectroscopy Enables High State of Charge Diagnostics.

Monitoring the precise lithium inventory of the graphitic carbon electrode within the Li-ion battery, in order to assess cell aging, has remained challenging. Herein, operando electrochemical Kerr-gated Raman spectroscopy measurements on microcrystalline graphite during complete lithium insertion and extraction are reported and compared to conventional continuous-wave Raman microscopy. Suppression of the fluorescence emission signals via use of the Kerr gate enabled the measurement of the Raman graphitic bands of highly lithiated graphite where 0.

Disentangling subjective symptom complaints and objective cognitive performance in veterans: Impact of posttraumatic stress disorder and lifetime traumatic brain injury burden.

Self-reported histories of mild traumatic brain injury (mTBI) and posttraumatic stress disorder (PTSD) symptoms are prevalent among post-9/11 veterans. Both are associated with subjective and often overlapping symptom complaints, but variably with objective neuropsychological test performances. These outcomes are seldom explored in relation to lifetime mTBI burden.

Development of the United States Environmental Protection Agency's Facilities Status Dashboard for the COVID-19 Pandemic: Approach and Challenges.

Develop a tool for applying various COVID-19 re-opening guidelines to the more than 120 U.S. Environmental Protection Agency (EPA) facilities.

A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode.

Electrochemically active covalent organic frameworks (COFs) are promising electrode materials for Li-ion batteries. However, improving the specific capacities of COF-based electrodes requires materials with increased conductivity and a higher concentration of redox-active groups. Here, we designed a series of pyrene-4,5,9,10-tetraone COF (PT-COF) and carbon nanotube (CNT) composites (denoted as PT-COFX, where = 10, 30, and 50 wt % of CNT) to address these challenges.

Rilzabrutinib, an Oral BTK Inhibitor, in Immune Thrombocytopenia.

Background: Rilzabrutinib, an oral, reversible covalent inhibitor of Bruton's tyrosine kinase, may increase platelet counts in patients with immune thrombocytopenia by means of dual mechanisms of action: decreased macrophage (Fcγ receptor)-mediated platelet destruction and reduced production of pathogenic autoantibodies.

Methods: In an international, adaptive, open-label, dose-finding, phase 1-2 clinical trial, we evaluated rilzabrutinib therapy in previously treated patients with immune thrombocytopenia. We used intrapatient dose escalation of oral rilzabrutinib over a period of 24 weeks; the lowest starting dose was 200 mg once daily, with higher starting doses of 400 mg once daily, 300 mg twice daily, and 400 mg twice daily.

A thorough QTc study to evaluate the effects of oral rilzabrutinib administered alone and with ritonavir in healthy subjects.

This study aimed to define the clinically relevant supratherapeutic dose of rilzabrutinib, an oral Bruton tyrosine kinase (BTK) inhibitor, and evaluate potential effects of therapeutic and supratherapeutic exposures on cardiac repolarization in healthy subjects. This was a two-part phase I study (anzctr.org.

Demographic survey of private veterinary practices in western Canada.

A workforce survey of private veterinary practices in western Canada was conducted in 2020. Data were obtained on 526 practices (response rate = 39.5%) and 1445 individual veterinary practitioners.

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability.

Extended anionic frameworks based on condensation of polyhedral main group non-metal anions offer a wide range of structure types. Despite the widespread chemistry and earth abundance of phosphates and silicates, there are no reports of extended ultraphosphate anions with lithium. We describe the lithium ultraphosphates LiPO and LiPO based on extended layers and chains of phosphate, respectively.

Element selection for crystalline inorganic solid discovery guided by unsupervised machine learning of experimentally explored chemistry.

The selection of the elements to combine delimits the possible outcomes of synthetic chemistry because it determines the range of compositions and structures, and thus properties, that can arise. For example, in the solid state, the elemental components of a phase field will determine the likelihood of finding a new crystalline material. Researchers make these choices based on their understanding of chemical structure and bonding.

Trapped interfacial redox introduces reversibility in the oxygen reduction reaction in a non-aqueous Ca electrolyte.

Electrochemical investigations of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) have been conducted in a Ca-containing dimethyl sulfoxide electrolyte. While the ORR appears irreversible, the introduction of a tetrabutylammonium perchlorate (TBAClO) co-salt in excess concentrations results in the gradual appearance of a quasi-reversible OER process. Combining the results of systematic cyclic voltammetry investigations, the degree of reversibility depends on the ion pair competition between Ca and TBA cations to interact with generated superoxide (O ).