Publications by authors named "Nattawut Osakoo"

With the growing necessity of achieving carbon neutrality in the industrial sector, the catalytic hydrogenation of carbon dioxide into methanol has been widely considered one of the key strategies for the utilization of captured CO. For this reason, the development of alternative catalysts such as ZnZrO has attracted considerable interest, given its superior stability and versatility in comparison to the conventional Cu-based materials. In this work, ZnZrO has been produced by a hydrothermal synthesis method at varied synthesis pH between 7 and 10 and a positive association between pH and catalytic CO conversion is observed.

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Heterogeneous catalysts consisting of potassium supported on zeolites are active for transesterification, but the effect of zeolite properties is not clearly understood. This work compares catalysts containing 12 wt.% potassium on zeolite sodium A and X (12K/NaA and 12K/NaX) in terms of performance and physicochemical properties.

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Sugarcane bagasse ash (SCBA) is a solid waste containing a high amount of silica (SiO) and is suitable to utilize as a silica source for synthesizing zeolite NaA. SCBA is typically calcined at high temperatures before silica extraction. The method is not environmentally friendly because it consumes energy and produces CO.

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Zeolite NaY synthesized from a typical procedure could suffer from agglomeration. Adding non-refluxed cogon grass (NG) to the synthesis gel could produce NaY with good dispersion and uniform crystal size. Small molecules produced from cogon grass in alkaline conditions could prevent agglomeration.

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5-Hydroxymethylfurfural (5-HMF) synthesized through glucose conversion requires Lewis acid (L) site for isomerization and Brønsted acid (B) site for dehydration. The objective of this work is to investigate the influence of the metal type of Al-SBA-15-supported phosphates of Cr, Zr, Nb, Sr, and Sn on glucose conversion to 5-HMF in a NaCl-H O/n-butanol biphasic solvent system. The structural and acid property of all supported metal phosphate samples were fully verified by several spectroscopic methods.

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Zeolites in powder form have the potential to agglomerate, lowering access to active sites. Furthermore, a suspension of fine zeolite powder in liquid media is difficult to separate. Such drawbacks could be improved by dispersing zeolite crystals on support materials.

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