Ranking the Efficiency of Gas Hydrate Anti-agglomerants through Molecular Dynamic Simulations.

Using both computational and experimental methods, the capacity of four different surfactant molecules to inhibit the agglomeration of sII hydrate particles was assessed. The computational simulations were carried out using both steered and non-steered molecular dynamics (MD), simulating the coalescence process of a hydrate slab and a water droplet, both covered with surfactant molecules. The surfactants were ranked according to free energy calculations (steered MD) and the number of agglomeration events (non-steered MD).

Versatile phase transfer of gold nanoparticles from aqueous media to different organic media.

A novel, simple, and very efficient method to prepare hydrophobically modified gold particles is presented. Gold nanoparticles of different sizes and polydispersities were prepared. The diameter of the gold particles ranges from 5 to 37 nm.

Effects of counterions and co-ions on foam films stabilized by anionic dodecyl sulfate.

The influence of counterions and co-ions on the stability and thickness of foam films stabilized by anionic dodecyl sulfate (DS(-)) has been studied in a thin film pressure balance. Particularly, the effect on the properties of foam films of (i) the counterions Li(+), Na(+), and Cs(+) of DS(-) and (ii) monovalent inorganic salts added to sodium dodecyl sulfate solutions is considered. Generally, addition of salt improved the stability of the foam films.

Negative charges at the air/water interface and their consequences for aqueous wetting films containing surfactants.

Negative charges at the air/water interface have been proven previously by the authors via disjoining pressure measurements of wetting films. In the present study the surface charges of wetting film are modified in order to control the film stability. Studies at different pH values support the assumption that the negative charges are caused by an excess of hydroxide ions.