Chemical Evaluation and Performance Characterization of Pentaerythritol Tetranitrate (PETN) under Melt Conditions.

Pentaerythritol tetranitrate (PETN) is a nitrate ester explosive commonly used in commercial detonators. Although its degradation properties have been studied extensively, very little information has been collected on its thermal stability in the molten state due to the fact that its melting point is only ∼20 °C below its onset of decomposition. Furthermore, studies that have been performed on PETN thermal degradation often do not fully characterize or quantify the decomposition products.

Tracking Thermal Decomposition Chemistry in Secondary Solid Explosives with X-ray Diffraction.

We present an approach for measuring thermal decomposition kinetics in crystalline solids using X-ray diffraction to track the loss of crystallinity that accompanies condensed phase decomposition chemistry. We apply this method to systems for which extracting thermodynamic parameters has been historically difficult: organic molecular crystals that thermally decompose below their melting points, such as solid explosives. To demonstrate this method, we measured the rate of solid, thermal decomposition versus temperature in three different secondary solid explosives and the sugar fructose.