The impact of bioreduction on the remobilization of adsorbed cadmium Cd(II) on minerals, including hematite, goethite, and two iron(III)-rich clay minerals nontronites (NAU-1 and NAU-2) under anoxic conditions was investigated. Langmuir isotherm equation better described the sorption of Cd(II) onto the all minerals. The maximum adsorption capacity was 6.
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December 2015
Adsorption of As(V) on various clay minerals including kaolinite (KGa-1), montmorillonite (SWy-1) and nontronites (NAU-1 and NAU-2), and subsequent bioreduction of sorbed As(V) to As(III) by bacterium Shewanella putrefaciens strain CN-32 were investigated. Nontronites showed relatively higher sorption capacity for As(V) primarily due to higher iron oxide content. Freundlich equation well described the sorption of As(V) on NAU-1, NAU-2 and SWy-1, while As(V) sorption isotherm with KGa-1 fitted well in the Langmuir model.
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