Publications by authors named "Nasir Rafique"

Over the past few years, advanced oxidation processes (AOPs) have shown promising efficiencies for wastewater remediation. Carbocatalysis, in particular, has been exploited widely thanks to its sustainable and economical properties but has an issue of recovery and reusability of the catalysts. To address this, three-dimensional (3D) binary and ternary graphene-based composites in the form of macro discs were created to activate peroxymonosulfate (PMS) for catalytic oxidation of sulfamethoxazole (SMX).

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Membrane separation and sulfate radicals-based advanced oxidation processes (SR-AOPs) can be combined as an efficient technique for the elimination of organic pollutants. The immobilization of metal oxide catalysts on ceramic membranes can enrich the membrane separation technology with catalytic oxidation avoiding recovering suspended catalysts. Herein, nanostructured CoO ceramic catalytic membranes with different Co loadings were fabricated via a simple ball-milling and calcination process.

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Increasing water pollution has imposed great threats to public health, and made efficient monitoring and remediation technologies critical to a clean environment. In this study, a versatile heterojunction of Au nanoparticles modified phosphorus doped carbon nitride (Au/P-CN) is designed and fabricated. The Au/P-CN heterostructure demonstrates improved light absorption, rapid separation of charge carriers, and improved electrical conductivity.

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Rational design with fine-tuning of the electrocatalyst material is vital for achieving the desired sensitivity, selectivity, and stability for an electrochemical sensor. In this study, a three-dimensional (3D) hierarchical core-shell catalyst was employed as a self-standing, binder-free electrode for non-enzymatic glucose sensing. The catalyst was prepared by decorating the shell of NiFe layered double hydroxide (LDH) nanosheets (NSs) on the core of Cu nanowires (NWs) grown on a Cu foam support.

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Environmental remediation has become more effective when using nanotechnologies. In this study, iron oxide (α-FeO) nanospheres with different cobalt doping levels (xCo-FeO) were synthesised and applied in the heterogeneous activation of peroxymonosulfate (PMS) for the degradation of p-hydroxybenzoic acid (p-HBA). The catalyst (3Co-FeO) with 3% Co doping exhibits the best performance for PMS activation, possibly because of the larger specific surface area and the tailored catalyst surface as confirmed by X-ray photoelectron spectroscopy (XPS).

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