We show that flexible metal-organic frameworks (MOFs) exhibiting "gate openings/closings" for CO can intrinsically suppress the exothermic heat released by adsorption and the endothermic heat gained by desorption, both of which reduce the working capacity of CO in a separation process under near-adiabatic conditions. We use the elastic layer-structured metal-organic framework-11 (ELM-11) [Cu(4,4'-bipyridine)(BF)], which exhibits a two-step gate-adsorption isotherm, as a model system for flexible MOFs, and perform free energy analyses with the aid of grand canonical Monte Carlo simulations for ELM-11 structures that were determined by the Rietveld method using in situ synchrotron X-ray powder diffraction data. We demonstrate that the thermal management capabilities of ELM-11 showing the two-step gating for CO at lower and higher pressures are nearly identical and quite effective (41% and 44% at 298 K, respectively).
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