Electronic and steric substituent effects on the fluorescence emission of 2-pyrazoline derivatives.

A series of substituted 2-pyrazolines were synthesized, and the steric and electronic effects of substituents on the C - and C -positions of the heterocyclic ring on their fluorescent ability were investigated. Two different conjugative intramolecular charge transfer (ICT) and intramolecular charge transfer through space (spiro-conjugation) affect the fluorescence intensity of these compounds. The extent of the ICT process and spiro-conjugation depends on the electronic nature of the additional substitution and its position on the attached aryl rings.

Post-synthetic modifications of covalent organic frameworks (COFs) for diverse applications.

Covalent organic frameworks (COFs) are porous and crystalline organic polymers, which have found usage in various fields. These frameworks are tailorable through the introduction of diverse functionalities into the platform. Indeed, functionality plays a key role in their different applications.