Publications by authors named "Narendar Nasani"

In glasses, a sodium ion (Na) is a significant mobile cation that takes up a dual role, that is, as a charge compensator and also as a network modifier. As a network modifier, Na cations modify the structural distributions and create nonbridging oxygens. As a charge compensator, Na cations provide imbalanced charge for oxygen that is linked between two network-forming tetrahedra.

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Article Synopsis
  • One-dimensional Haldane gap materials, like rare earth barium chain nickelates, exhibit strong spin antiferromagnetic properties and unique structures that make them interesting for thermoelectric applications.
  • The material CaBaGdNiO shows impressive Seebeck coefficients of 140-280 μV K at high temperatures, maintained even with significant acceptor-substitution levels due to low dimensionality and electronic correlations.
  • Despite low thermal conductivities of around 1.5 W m K, ideal for thermoelectrics, the electrical conductivity of these materials is still insufficient, highlighting the need to improve electronic band structures and microstructural features to boost charge carrier mobility.
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This study highlights that Fe additives offer better catalytic properties than carbon, Fe-C (iron carbide/carbon composites), and Fe-Mg (Mg FeH ) additives for the low-temperature dehydrogenation of magnesium hydride. The in situ X-ray diffraction measurements prove the formation of a Mg FeH phase in iron additive loaded MgH . Nonetheless, differential scanning calorimetry data suggest that this Mg FeH phase does not have any influence on dehydrogenation properties of MgH .

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The present study aims to understand the catalysis of the MgH2 -Nb2 O5 hydrogen storage system. To clarify the chemical interaction between MgH2 and Nb2 O5 , the mechanochemical reaction products of a composite mixture of MgH2 +0.167 Nb2 O5 was monitored at different time intervals (2, 5, 15, 30, and 45 min, as well as 1, 2, 5, 10, 15, 20, 25, and 30 h).

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The current work demonstrates how tailoring the transport properties of thin ceria-based buffer layers in solid oxide fuel or electrolyser cells can provide the necessary phase stability against chemical interaction at the electrolyte/electrode interface, while also providing radical improvements in the electrochemical performance of the oxygen electrode. Half cells of Ce0.8R0.

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