Hydrogen-bonding interactions in 5-fluorocytosine-urea (2/1), 5-fluorocytosine-5-fluorocytosinium 3,5-dinitrosalicylate-water (2/1/1) and 2-amino-4-chloro-6-methylpyrimidine-6-chloronicotinic acid (1/1).

Three new compounds, namely, 5-fluorocytosine-urea (2/1), 2CHFNO·CHNO, (I), 5-fluorocytosine-5-fluorocytosinium 3,5-dinitrosalicylate-water (2/1/1), 2CHFNO·CHFNO·CHNO·HO, (II), and 2-amino-4-chloro-6-methylpyrimidine-6-chloronicotinic acid (1/1), CHClNO·CHClN, (III), have been synthesized and characterized by single-crystal X-ray diffraction. In compound (I), 5-fluorocytosine (5FC) molecules A and B form two different homosynthons [R(8) ring motif], one formed via N-H..

Supramolecular interactions in some organic hydrated 2,4,6-triaminopyrimidinium carboxylate and sulfate salts.

Four salts, namely, 2,4,6-triaminopyrimidinium 6-chloronicotinate dihydrate, CHN·CHClNO·2HO, (I), 2,4,6-triaminopyrimidinediium pyridine-2,6-dicarboxylate dihydrate, CHN·CHNO·2HO, (II), 2,4,6-triaminopyrimidinediium sulfate monohydrate, CHN·SO·HO, (III), and 2,4,6-triaminopyrimidinium 3,5-dinitrobenzoate dihydrate, CHN·CHNO·2HO, (IV), were synthesized and characterized by X-ray diffraction techniques. Proton transfer from the corresponding acid to the pyrimidine base has occurred in all four crystal structures. Of the four salts, two [(I) and (IV)] exist as monoprotonated bases and two [(II) and (III)] exist as diprotonated bases.