Reversible Electrochromic/Electrofluorochromic Dual Switching in Zn(II)-Based Metallo-Supramolecular Polymer Films.

The introduction of novel materials with multifunctional chromogenic properties, such as electrochromic/electrofluorochromic (EC/EFC) properties, has recently attracted prospective interest in the development of various optoelectronic devices and smart windows. In this study, a novel Zn(II)-based metallo-supramolecular polymer () has been developed as an ON/OFF switchable EFC application with prominent EC behavior. In this regard, the polymeric chain of was first synthesized by 1:1 complexation in a zigzag manner with Zn(II) ions at the metal center and 4,4'-[bis(2,2':6',2″-terpyridinyl)benzene]triphenylamine () as the redox-active ditopic ligand.

Diagnosis of bacterial infection in children with relapse of nephrotic syndrome: a personalized decision-analytic nomogram and decision curve analysis.

Background: Infections associated with nephrotic relapses (NR) are often managed according to physician preferences. A validated prediction tool will aid clinical decision-making and help in rationalizing antibiotic prescriptions. Our objective was to develop a biomarker-based prediction model and a regression nomogram for the prediction of the probability of infection in children with NR.

Seasonal variation of indoor radon, thoron and their progeny in Belagavi district of Karnataka, India.

Systematic investigations on the seasonal variation of indoor radon, thoron and their progeny levels have been carried out in Belagavi district of Karnataka, India. The radon and thoron levels were measured using LR-115 type II dosimeter in cups with single-entry pinhole. The measurements were carried out in all the four season, viz, monsoon, autumn, winter and summer, in selected houses of the region.

Cell-cell adhesions in embryonic stem cells regulate the stability and transcriptional activity of β-catenin.

E-cadherin (CDH1) is involved in maintaining cell-cell adhesions in embryonic stem cells (ESCs). However, its function in the context of cell fate decisions is largely unknown. Using mouse ESCs (mESCs), we demonstrate that E-cadherin and β-catenin interact at the membrane and continue to do so upon internalization within the cell.

An effective strategy for the development of multiferroic composite nanostructures with enhanced magnetoelectric coupling performance: a perovskite-spinel approach.

An energy efficient move toward the regulation of magnetization vector solely with E-field by developing multiferroic (MF) magnetoelectric (ME) nanostructures' have opened up vast avenues for novel low power consumption memories and magnetoelectric devices. The present study delineates the development of multiferroic nanocomposites (MF NCs) with perovskite BiFeO and spinel NiFeO. A simple Pechini one-pot method is employed for the preparation of nanocomposites with different molar concentrations and the modified structural, magnetic, dielectric, and magnetoelectric performance of NCs is carried out at room temperature.

Co(CO) as a Solid CO (g) Source for the Amino Carbonylation of (Hetero)aryl Halides with Highly Deactivated (Hetero)arylamines.

Carbonylation of (hetero)aryl iodides/bromides with highly deactivated 2-aminopyridines using Pd-Co(CO) bimetallic catalysis is accomplished. The use of Co(CO) as a solid CO(g) source enhanced reaction rates observed when compared to CO(g), and excellent yields highlight the versatility of the developed protocol. A wide range of electronically and sterically demanding heterocyclic amines and (hetero)aryl iodides/bromides employed for this study resulted in excellent yields of amino carbonylated products.

Electrochromic Os-based metallo-supramolecular polymers: electronic state tracking by XAFS, IR, and impedance spectroscopies.

In this study, the electronic states of Os-based metallo-supramolecular polymers (poly(OsL)) during electrochromism were tracked by X-ray absorption fine structure (XAFS), infrared (IR), and impedance spectroscopies. The XAFS spectra suggested electronic charge migration in the polymer, and the spectra revealed reversible changes caused by electrochemical redox reactions. The IR spectra of the polymers showed an IVCT band, and we also confirmed the reversible changes by applying a voltage to the redox cell.

Clathrin-Mediated Endocytosis Regulates a Balance between Opposing Signals to Maintain the Pluripotent State of Embryonic Stem Cells.

Endocytosis is implicated in the maintenance of embryonic stem cell (ESC) pluripotency, although its exact role and the identity of molecular players remain poorly understood. Here, we show that the clathrin heavy chain (CLTC), involved in clathrin-mediated endocytosis (CME), is vital for maintaining mouse ESC (mESC) pluripotency. Knockdown of Cltc resulted in a loss of pluripotency accompanied by reduced E-cadherin (E-CAD) levels and increased levels of transforming growth factor β (TGF-β) and extracellular signal-regulated kinase (ERK) signaling.

Modulation of a coordination structure in a europium(iii)-based metallo-supramolecular polymer for high proton conduction.

Developing high proton conducting solid materials is significant in the field of fuel cells. A europium(iii)-based metallo-supramolecular polymer with uncoordinated carboxylic acids (PolyEu-H) was successfully synthesized by modifying the synthesis conditions. The proton conductivity was enhanced with increasing the relative humidity (RH) from 30 to 95% RH.

Slow magnetic relaxation in a Tb(iii)-based coordination polymer.

A Tb(iii)-based coordination polymer (polyTb) was synthesized by complexation of Tb(NO3)3·(6H2O) and 4',4''''-[1,1'-biphenyl]-4,4'-diylbis[6,6''-bis(ethoxycarbonyl)2':6',2''-terpyridine](L). The polymer structure was determined by Job's plots, DFT calculation, and X-ray absorption fine structure (XAFS) measurement. Job's plots indicated that the mole ratio (Tb ion : L) is 1 : 1.

Distribution of natural radionuclides and radon concentration in the riverine environs of Cauvery, South India.

Systematic studies were carried out to understand the distribution of natural radionuclides in sediments and radon in water in the riverine environs of Cauvery, one of the major rivers of South India. The activity of radionuclides in the sediment was measured by gamma ray spectrometry. The radon emanation from the sediment was measured by the sealed 'can technique' and the radon in the water was measured using the RAD-7 instrument.

Synthesis of a novel glucose capped gold nanoparticle as a better theranostic candidate.

Gold nanoparticles are predominantly used in diagnostics, therapeutics and biomedical applications. The present study has been designed to synthesize differently capped gold nanoparticles (AuNps) by a simple, one-step, room temperature procedure and to evaluate the potential of these AuNps for biomedical applications. The AuNps are capped with glucose, 2-deoxy-D-glucose (2DG) and citrate using different reducing agents.

Two-Photon Luminescence and Second-Harmonic Generation in Organic Nonlinear Surface Comprised of Self-Assembled Frustum Shaped Organic Microlasers.

An ultrathin nonlinear optical (NLO) organic surface composed of numerous self-assembled frustum-shaped whispering-gallery-mode resonators displays both two-photon luminescence and second-harmonic-generation signals. A super-second-order increase of the NLO intensity with respect to pump power confirms the microlasing action and practical usefulness of the NLO organic surfaces.

NATURAL RADIOACTIVITY IN SEDIMENTS AND RIVER BANK SOIL OF KALLADA RIVER OF KERALA, SOUTH INDIA AND ASSOCIATED RADIOLOGICAL RISK.

The paper presents the activity concentrations of Th, Ra and K in the sediments and river bank soil samples collected from the Kallada river environs of coastal Kerala. The radiological risks associated with these radionuclides were calculated. The samples were processed following standard procedure, and activity was counted using a high-efficiency 5″ × 5″ NaI (Tl) detector coupled to GSPEC gamma spectroscopy system.

NATURAL RADIONUCLIDE LEVELS IN SEDIMENTS OF CAUVERY RIVERINE ENVIRONMENT.

The paper presents the systematic measurement of activity concentrations of K, Ra and Th in sediment sample of Cauvery river of Karnataka, South India. Activity was measured using HpGe gamma ray spectrometer, and the mean values of K, Ra and Th in the sediment samples were found to be 144.31, 32.

DISTRIBUTION OF 210PO IN HEMAVATHI RIVERINE ENVIRONMENT.

In the present investigation, the concentration of Po was measured in soil and sediment samples from riverine environment of Hemavathi river of south Karnataka. The Po in the samples was separated by radiochemical method, and the activity was counted using ZnS(Ag) alpha counter. Seasonal variation of Po was studied for soil and sediment samples.

RADIUM AND RADON EXHALATION RATE IN SOIL SAMPLES OF HASSAN DISTRICT OF SOUTH KARNATAKA, INDIA.

The radon exhalation rate was measured in 32 soil samples collected from Hassan district of South Karnataka. Radon exhalation rate of soil samples was measured using can technique. The results show variation of radon exhalation rate with radium content of the soil samples.

Visible-Near-Infrared Range Whispering Gallery Resonance from Photonic μ-Sphere Cavities Self-Assembled from a Blend of Polystyrene and Poly[4,7-bis(3-octylthiophene-2-yl)benzothiadiazole-co-2,6-bis(pyrazolyl)pyridine] Coordinated to Tb(acac)3.

A novel red emitting copolymer (P1) was prepared (Mn ∼ 10.7 kDa) by copolymerizing tridentate ligand, namely 2,6-bis(pyrazolyl)pyridine (BPP) with 4,7-bis(2-ethynyl-5-thienyl)-2,1,3-benzothiadiazole. This copolymer readily formed an orange yellow emitting metal containing conjugated polymer (P1.

Inheritance of pigeonpea sterility mosaic disease resistance in pigeonpea.

A comprehensive study was conducted using PPSMV resistant (BSMR 736) and susceptible (ICP 8863) genotypes to develop a segregating population and understand the inheritance of PPSMV resistance. The observed segregation was comparable to 13 (susceptible): 3 (resistant). Hence, the inheritance was controlled by two genes, SV1 and SV2, with inhibitory gene interaction.

Molecular mapping of genomic regions harbouring QTLs for root and yield traits in sorghum (Sorghum bicolor L. Moench).

Root system is a vital part of plants for absorbing soil moisture and nutrients and it influences the drought tolerance. Identification of the genomic regions harbouring quantitative trait loci (QTLs) for root and yield traits, and the linked markers can facilitate sorghum improvement through marker-assisted selection (MAS) besides the deeper understanding of the plant response to drought stress. A population of 184 recombinant inbred lines (RILs), derived from E36-1 × SPV570, along with parents were phenotyped for component traits of yield in field and root traits in an above ground rhizotron.

Highly fluorescent GFPm 2+ -based genome integration-proficient promoter probe vector to study Mycobacterium tuberculosis promoters in infected macrophages.

Study of activity of cloned promoters in slow-growing Mycobacterium tuberculosis during long-term growth conditions in vitro or inside macrophages, requires a genome-integration proficient promoter probe vector, which can be stably maintained even without antibiotics, carrying a substrate-independent, easily scorable and highly sensitive reporter gene. In order to meet this requirement, we constructed pAKMN2, which contains mycobacterial codon-optimized gfp(m) (2+) gene, coding for GFP(m) (2+) of highest fluorescence reported till date, mycobacteriophage L5 attP-int sequence for genome integration, and a multiple cloning site. pAKMN2 showed stable integration and expression of GFP(m) (2+) from M.