Synthesis, Properties, and Techno-economic Analysis of Highly Stable Biotransformer Oil Derived from Transesterification of Palm Oil Methyl Esters and Ditrimethylolpropane.

Currently, biotransformer oil (BTO) is in high demand due to the increasing level of electrical power consumption and environmental policy. Hence, this research aimed to prepare a highly stable BTO via basic transesterification of palm oil methyl ester (POME) and ditrimethylolpropane (Di-TMP) catalyzed by sodium methoxide (NaOCH). Under the optimal conditions (POME/Di-TMP molar ratio = 5.

Hydrodeoxygenation of Oxygenates Derived from Biomass Pyrolysis Using Titanium Dioxide-Supported Cobalt Catalysts.

Bio-oil upgrading to produce biofuels and chemicals has become an attractive topic over the past decade. However, the design of cost- and performance-effective catalysts for commercial-scale production remains a challenge. Herein, commercial titania (TiO) was used as the support of cobalt (Co)-based catalysts (Co/TiO) due to its low cost, high availability, and practicability for commercialization in the future.

Development and Application of a Novel Multiloop Splitter-Based Non-cryogenic Artificial Trapping Modulation System in Comprehensive Two-Dimensional Gas Chromatography.

A multiloop splitter-based non-cryogenic artificial trapping (M-SNAT) modulation technique was established, which applied the first (D) nonpolar and the second (D) polar columns, deactivated fused silica (DFS) columns, a microfluidic Deans switch (DS), and splitters located between the D column outlet and the DS. The splitters were connected into multiple loops with a progressively doubled perimeter of the next loop. This enabled a duplex splitting mechanism within each loop consisting of splitting of analyte pulses, the pulse delay, and their combination which led to equally split peaks of the same analytes with the number of split peaks () equal to 2 ( = number of loops).

Recovery of Arenes from Polyethylene Terephthalate (PET) over a Co/TiO Catalyst.

Upcycling of spent plastics has become a more emergent topic than ever before due to the rapid generation of plastic waste associated with the change of lifestyles of the human society. Polyethylene terephthalate (PET) is a major aromatic plastic and herein, the conversion of PET back into arenes was demonstrated in a one-pot reaction combining depolymerization and hydrodeoxygenation (HDO) over a Co/TiO catalyst. The effectiveness of the Co/TiO catalyst in HDO and the underlining reaction pathway were established using the PET monomer terephthalic acid (TPA) as the substrate.

Single- and two-step hydrothermal liquefaction of microalgae in a semi-continuous reactor: Effect of the operating parameters.

This work investigated an influence of operating conditions on the biocrude yield and properties obtained from hydrothermal liquefaction (HTL) of Coelastrum sp. microalgae in a two-step sequential HTL (THTL) and a single-step HTL (SHTL) using a semi-continuous system. A higher biocrude yield with a lower nitrogen content was obtained with the THTL process than the SHTL one.

Pt/Al₂O₃-catalytic deoxygenation for upgrading of Leucaena leucocephala-pyrolysis oil.

The aim of this study was to improve the quality of bio-oil produced from the pyrolysis of Leucaena leucocephala trunks via catalytic deoxygenation using Pt/Al2O3 (Pt content=1.32% (w/w)). The minimum molar ratio of oxygen/carbon (O/C) at 0.