An ionic liquid domain was successfully prepared outside double-stranded DNA by fixing 1-alkyl-3-methyl-imidazolium (C(n)MI) cations on the phosphate groups of DNA. First, four species of ionic liquid were made using phosphoric acid di-n-butyl ester and C(n)MI (n=2,4,8, and 12) as a low molecular weight model. They were obtained as liquid salts, and their ionic conductivity ranged up to 10(-5)Scm(-1) at 50 degrees C.
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