Pyrene-attached new Schiff base polymer: ACQ to AIE conversion and its prospects.

Schiff base polymer (SBP) is a new research field and an excellent candidate for real-life applications such as photoresistors, fluorescent chemical sensing kits, electrochromic devices, flame-retarders, and electrochemical substances. The dye-containing SBP (DSBP) advances the material further. Herein, the quality of pyrene dye has been improved through its chemical attachment to polyethyleneimine by a facile Schiff base reaction.

The photodynamic approach to the molecular-level origin of metal-guided photochromism and ultrafast absorption spectroscopy.

Metal-guided photochromic material (photochromic complex) is one of the latest versions of photo-responsive materials due to their smart behaviour and promising real-world applications. The present work explores the molecular-level origin of metal-guided photochromism using a photodynamic approach and ultrafast absorption spectroscopy, to address all existing lacunas. Here, rhodamine B (RhB) dye containing the Schiff base zinc complex is considered a representative photochromic complex for both theoretical treatment and experimental observations.